Photobiocatalytic strategies for organic synthesis

MA Emmanuel, SG Bender, C Bilodeau… - Chemical …, 2023 - ACS Publications
Biocatalysis has revolutionized chemical synthesis, providing sustainable methods for
preparing various organic molecules. In enzyme-mediated organic synthesis, most reactions …

Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Carboxylic acids as adaptive functional groups in metallaphotoredox catalysis

SB Beil, TQ Chen, NE Intermaggio… - Accounts of chemical …, 2022 - ACS Publications
Conspectus The development of palladium-catalyzed cross-coupling methods for the
activation of C (sp2)–Br bonds facilitated access to arene-rich molecules, enabling a …

Photocatalysis in the life science industry

L Candish, KD Collins, GC Cook, JJ Douglas… - Chemical …, 2021 - ACS Publications
In the pursuit of new pharmaceuticals and agrochemicals, chemists in the life science
industry require access to mild and robust synthetic methodologies to systematically modify …

A Paradigm Shift in Catalysis: Electro-and Photomediated Nickel-Catalyzed Cross-Coupling Reactions

MD Palkowitz, MA Emmanuel… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Transition-metal catalyzed cross-coupling reactions are fundamental reactions
in organic chemistry, facilitating strategic bond formations for accessing natural products …

Nickel and palladium catalysis: Stronger demand than ever

VM Chernyshev, VP Ananikov - Acs Catalysis, 2022 - ACS Publications
Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

The merger of transition metal and photocatalysis

J Twilton, C Le, P Zhang, MH Shaw, RW Evans… - Nature Reviews …, 2017 - nature.com
The merger of transition metal catalysis and photocatalysis, termed metallaphotocatalysis,
has recently emerged as a versatile platform for the development of new, highly enabling …

Imidazophenothiazine-Based Thermally Activated Delayed Fluorescence Materials with Ultra-Long-Lived Excited States for Energy Transfer Photocatalysis

R Hojo, K Bergmann, SA Elgadi… - Journal of the …, 2023 - ACS Publications
Triplet-triplet energy transfer (EnT) is a powerful activation pathway in photocatalysis that
unlocks new organic transformations and improves the sustainability of organic synthesis …

The importance of synthetic chemistry in the pharmaceutical industry

KR Campos, PJ Coleman, JC Alvarez, SD Dreher… - Science, 2019 - science.org
BACKGROUND Over the past century, innovations in synthetic chemistry have greatly
enabled the discovery and development of important life-changing medicines, improving the …