Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

In recent years, the integration of photocatalytic hydrogen atom transfer (HAT) with transition
metal catalysis has emerged as a formidable strategy for the construction of C (sp3)–carbon …

Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for
the generation and handling of reactive intermediates. PEC permits selective single …

The Minisci alkylation of N‐heteroarenes with unactivated alkanes under external oxidant‐
free conditions provides an economically attractive route to access alkylated N …

Many contemporary organic transformations, such as Ni-catalyzed cross-electrophile
coupling (XEC), require a reductant. Typically, heterogeneous reductants, such as Zn0 or …

Metallaphotoredox catalysis merging photocatalysis and transition metal catalysis is now the
most efficient platform for sp 3 C–H functionalizations due to its very efficient activation and …

The external oxidant-free exploitation of abundant alkane feedstocks as alkyl radical
precursors remains a topic of high interest in synthetic communities. Here, we report a Ce …

The reductive activation of chemical bonds at less negative potentials provides a foundation
for high functional group tolerance and selectivity, and it is one of the central topics in …

Enantioselective transformations of hydrocarbons to three-dimensional chiral molecules
remain a significant challenge in synthetic chemistry. This study uses asymmetric paired …

Photocatalytic CO2 reduction into C1 products is one of the most trending research subjects
of current times as sustainable energy generation is the utmost need of the hour. In this …