Why do lithium–oxygen batteries fail: parasitic chemical reactions and their synergistic effect
As an electrochemical energy‐storage technology with the highest theoretical capacity,
lithium–oxygen batteries face critical challenges in terms of poor stabilities and low …
lithium–oxygen batteries face critical challenges in terms of poor stabilities and low …
Review of electrochemical oxidation desulfurization for fuels and minerals
T Zhang, J Zhang, Z Wang, J Liu, G Qian, D Wang… - Fuel, 2021 - Elsevier
Electro-oxidation desulfurization uses reactive oxygen species (ROSs) from water
electrolysis to strengthen the transition of sulfur-containing phase, enhancing the separation …
electrolysis to strengthen the transition of sulfur-containing phase, enhancing the separation …
Chemical instability of dimethyl sulfoxide in lithium–air batteries
DG Kwabi, TP Batcho, CV Amanchukwu… - The journal of …, 2014 - ACS Publications
Although dimethyl sulfoxide (DMSO) has emerged as a promising solvent for Li–air
batteries, enabling reversible oxygen reduction and evolution (2Li+ O2⇔ Li2O2), DMSO is …
batteries, enabling reversible oxygen reduction and evolution (2Li+ O2⇔ Li2O2), DMSO is …
Experimental and Computational Analysis of the Solvent‐Dependent O2/Li+‐O2− Redox Couple: Standard Potentials, Coupling Strength, and Implications for …
DG Kwabi, VS Bryantsev, TP Batcho… - Angewandte …, 2016 - Wiley Online Library
Understanding and controlling the kinetics of O2 reduction in the presence of Li+‐containing
aprotic solvents, to either Li+‐O2− by one‐electron reduction or Li2O2 by two‐electron …
aprotic solvents, to either Li+‐O2− by one‐electron reduction or Li2O2 by two‐electron …
Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a Li–air battery
N Mozhzhukhina, LP Méndez De Leo… - The Journal of Physical …, 2013 - ACS Publications
In situ infrared subtractive normalized Fourier transform infrared spectroscopy (SNIFTIRS)
experiments performed simultaneously with the electroreduction of oxygen on gold and …
experiments performed simultaneously with the electroreduction of oxygen on gold and …
Controlling solution-mediated reaction mechanisms of oxygen reduction using potential and solvent for aprotic lithium–oxygen batteries
DG Kwabi, M Tułodziecki, N Pour, DM Itkis… - The Journal of …, 2016 - ACS Publications
Fundamental understanding of growth mechanisms of Li2O2 in Li–O2 cells is critical for
implementing batteries with high gravimetric energies. Li2O2 growth can occur first by 1e …
implementing batteries with high gravimetric energies. Li2O2 growth can occur first by 1e …
Effect of electrolyte concentration on the solvation structure of gold/LiTFSI–DMSO solution interface
The use of high-concentration electrolytes in lithium metal batteries enables the effective
suppression of lithium dendrite growth at the lithium anode. The issue of the solvation …
suppression of lithium dendrite growth at the lithium anode. The issue of the solvation …
The mechanisms of oxygen reduction and evolution reactions in nonaqueous lithium–oxygen batteries
A fundamental understanding of the mechanisms of both the oxygen reduction reaction
(ORR) and the oxygen evolution reaction (OER) in nonaqueous lithium–oxygen (Li–O2) …
(ORR) and the oxygen evolution reaction (OER) in nonaqueous lithium–oxygen (Li–O2) …
Role of Superoxide and Singlet Oxygen on the Oxygen Reduction Pathways in Li−O2 Cathodes at Different Li+ Ion Concentration**
The oxygen reduction reaction (ORR) on Au electrodes has been studied in DMSO at
different Li+ concentrations. In‐operando fluorescence decay of 9, 10‐dimethyl anthracene …
different Li+ concentrations. In‐operando fluorescence decay of 9, 10‐dimethyl anthracene …
Oxygen reduction and oxygen evolution in DMSO based electrolytes: The role of the electrocatalyst
In the present paper the role of the electrode material in oxygen reduction in DMSO based
electrolytes is elucidated using DEMS. We have found, employing platinum, gold, ruthenium …
electrolytes is elucidated using DEMS. We have found, employing platinum, gold, ruthenium …