The Bouguer‐Beer‐Lambert law: Shining light on the obscure

TG Mayerhöfer, S Pahlow, J Popp - ChemPhysChem, 2020 - Wiley Online Library
Abstract The Beer‐Lambert law is unquestionably the most important law in optical
spectroscopy and indispensable for the qualitative and quantitative interpretation of …

Infrared spectroscopic imaging advances as an analytical technology for biomedical sciences

TP Wrobel, R Bhargava - Analytical chemistry, 2018 - ACS Publications
Optical chemical imaging seeks to nondestructively acquire spatially resolved chemical
information without the use of labels or probes. The combination of vibrational mid-infrared …

Application of vibrational spectroscopy and imaging to point-of-care medicine: a review

S Pahlow, K Weber, J Popp, BR Wood… - Applied …, 2018 - journals.sagepub.com
Vibrational spectroscopy and imaging promise molecular information that can be rapidly
acquired without the need for specialized stains or dyes, thereby potentially simplifying and …

Comprehensive thematic T-matrix reference database: a 2017–2019 update

MI Mishchenko - Journal of Quantitative Spectroscopy and Radiative …, 2020 - Elsevier
Since its inception in the mid-1960s, the T-matrix method has been one of the most versatile
and efficient numerically exact computer solvers of the time-harmonic macroscopic Maxwell …

Resolution limit in infrared chemical imaging

Y Phal, L Pfister, PS Carney… - The Journal of Physical …, 2022 - ACS Publications
Chemical imaging combines the spatial specificity of optical microscopy with the spectral
selectivity of vibrational spectroscopy. Mid-infrared (IR) absorption imaging instruments are …

Deep learning for 'artefact'removal in infrared spectroscopy

S Guo, T Mayerhöfer, S Pahlow, U Hübner, J Popp… - Analyst, 2020 - pubs.rsc.org
It has been well recognized that infrared spectra of microscopically heterogeneous media do
not merely reflect the absorption of the sample but are influenced also by geometric factors …

Deviations from Beer's law on the microscale–nonadditivity of absorption cross sections

TG Mayerhöfer, S Höfer, J Popp - Physical Chemistry Chemical …, 2019 - pubs.rsc.org
Beer's law assumes a linear dependence of absorbance on concentration, accordingly the
index of absorption and the molar attenuation coefficient are material properties and the …

Quantitative evaluation of infrared absorbance spectra–Lorentz profile versus Lorentz oscillator

TG Mayerhöfer, J Popp - ChemPhysChem, 2019 - Wiley Online Library
We present the theoretical basis for a profound upgrade of the method of absorbance band
fitting (“band deconvolution”), which requires only minute changes in the code of …

The effect of deformation of absorbing scatterers on Mie-type signatures in infrared microspectroscopy

MA Brandsrud, R Blümel, JH Solheim, A Kohler - Scientific reports, 2021 - nature.com
Mie-type scattering features such as ripples (ie, sharp shape-resonance peaks) and wiggles
(ie, broad oscillations), are frequently-observed scattering phenomena in infrared …

Structure and assembly mechanism of a centipede-shaped high-nuclear Dy 14 Cu 12 heterometallic nanocluster

S Yu, H Hu, Z Qiu, Y Zhang, D Liu, Y Liang, HH Zou… - …, 2023 - pubs.rsc.org
The assembly studies of high-nuclear clusters have received much interest in recent years
due to their targeted synthesis for some special usages. A Schiff base ligand 2-[N-(2 …