Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

Conspectus Cross-electrophile coupling, the cross-coupling of two different electrophiles,
avoids the need for preformed carbon nucleophiles, but development of general methods …

Cross-coupling between two similar or identical functional groups to form a new C–C bond
is a powerful tool to rapidly assemble complex molecules from readily available building …

Nickel-catalyzed reductive cross-coupling reactions have emerged as powerful methods to
join two electrophiles. These reactions have proven particularly useful for the coupling of sec …

The pervasive occurrence of saturated stereogenic carbon centers in pharmaceuticals,
agrochemicals, functional organic materials, and natural products has stimulated great …

The recent success of nickel catalysts in stereoconvergent cross-coupling and cross-
electrophile coupling reactions partly stems from the ability of monovalent nickel species to …

Herein, an electrochemically driven NiH‐catalyzed reductive coupling of alkyl halides and
alkyl alkenes for the construction of Csp3− Csp3 bonds is firstly reported. Notably, alkyl …

A Ni-catalyzed enantioselective reductive diarylation of activated alkenes by domino
cyclizative/cross-coupling of two aryl bromides is developed. This reaction proceeds under …

The formation of C–C bonds directly by catalytic reductive cross-coupling of two different
electrophiles represents one of the practical synthetic protocols that differs from the …

A critical overview of the catalytic joining of two different electrophiles, cross-electrophile
coupling (XEC), is presented with an emphasis on the central challenge of cross-selectivity …