Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Electrochemistry has emerged as a powerful means to enable redox transformations in
modern chemical synthesis. This tutorial review delves into the unique advantages of …

Achieving selective sensing toward target volatile organic compound gases is of vital
importance in the fields of air quality assessment, food freshness evaluation, and diagnosis …

Reaction conditions that are generally applicable to a wide variety of substrates are highly
desired, especially in the pharmaceutical and chemical industries,,,,–. Although many …

We report the development of oxoammonium-catalyzed oxidation of N-substituted amines
via a hydride transfer mechanism. Steric and electronic tuning of catalyst led to …

Data science is assuming a pivotal role in guiding reaction optimization and streamlining
experimental workloads in the evolving landscape of synthetic chemistry. A discipline-wide …

Transition-metal-catalyzed enantioselective functionalization of acyl radicals has so far not
been realized, probably due to their relatively high reactivity, which renders the chemo-and …

Cracking the selectivity–generality paradox is among the most pressing challenges in
asymmetric catalysis. This obstacle prevents the immediate and successful translation of …

With over 10,000 new reaction protocols arising every year, only a handful of these
procedures transition from academia to application. A major reason for this gap stems from …

Hydride abstraction represents a promising yet underexplored approach in the
functionalization of C–H bonds. In this work, we report the oxidation of α-C–H bonds of …