For an atom with such a uniquely simple electronic makeup, hydrogen shows remarkable
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …

Abstract Complexes of Group 2, 12, 13, 14, 15 and 16 elements with mono-, bi-, and poly-
dentate phosphine and arsine ligands (and including the very few examples of stibine and …

Tertiary amine adducts of alane show a diverse range of structures based on four and five
coordinate species, hydride bridging dimeric and polymeric species, and ionic species …

Bulky substituents at the main group atoms are necessary for the synthesis of monomeric
phosphanylalanes and-gallanes of the type A.[1] In contrast to the strong π bonding in B±N …

The dimers of [H3N⊙ BH3] 2,[H3N⊙ AlH3] 2, and [H3N⊙ GaH3] 2 are characterized as
head-to-tail complexes with intermolecular H− H hydrogen bonding. In the case of [H3N⊙ …

The development of organoaluminum chemistry has largely been driven by the use of these
materials in catalysis. Currently, new but not less sophisticated utilizations have emerged …

A family of complexes of N-methylmorpholinium metal halides has been synthesized and
analyzed using X-ray crystallography and temperature dependant magnetic susceptibility …

The occurrence of dihydrogen bonds in the complexes and dimers of complexes involving
the main group elements is systematically investigated. The complexes of LiH, BH3, and …

Thermally robust expanded ring carbene adducts of AlH3 have been synthesized with a
view to probing their ligating abilities via Al–H σ-bond coordination. While κ2 binding to the …

Two aspects of Group 13 metal chemistry are surveyed in the light of recent research,
particularly that reported in the period 1992–1998. The first concerns compounds containing …