“Functional upcycling” of polymer waste towards the design of new materials

O Guselnikova, O Semyonov, E Sviridova… - Chemical Society …, 2023 - pubs.rsc.org
Diversification of polymer waste recycling is one of the solutions to improve the current
environmental scenario. Upcycling is a promising strategy for converting polymer waste into …

Sustainable developments in polyolefin chemistry: Progress, challenges, and outlook

XY Wang, Y Gao, Y Tang - Progress in Polymer Science, 2023 - Elsevier
Polyolefins are the largest-scale synthetic plastics and play a key role in modern society.
Their production consumes huge amounts of fossil-derived monomer feedstocks, which …

Polyolefins and polystyrene as chemical resources for a sustainable future: challenges, advances, and prospects

CWS Yeung, JYQ Teo, XJ Loh, JYC Lim - ACS Materials Letters, 2021 - ACS Publications
Nonbiodegradable plastics with inert and saturated C–C backbones comprise the majority of
global annual plastics produced, including the ubiquitous polyolefins (polyethylene and …

Sustainable chemical upcycling of waste polyolefins by heterogeneous catalysis

M Chu, W Tu, S Yang, C Zhang, Q Li, Q Zhang… - SusMat, 2022 - Wiley Online Library
The mass production of disposable polyolefin products has led to serious plastic pollution
and an imbalance between manufacturing and recycling. Given these challenges, the …

Diverse functional polyethylenes by catalytic amination

NR Ciccia, JX Shi, S Pal, M Hua, KG Malollari… - Science, 2023 - science.org
Functional polyethylenes possess valuable bulk and surface properties, but the limits of
current synthetic methods narrow the range of accessible materials and prevent many …

C− H functionalization of commodity polymers

JB Williamson, SE Lewis, RR Johnson III… - Angewandte Chemie …, 2019 - Wiley Online Library
Synthetic manipulation of polymer substrates is one of the oldest and most reliable methods
to increase the functional diversity of soft materials. Modifying the chemical structure of …

Carbocyclic-fused N, N, N-pincer ligands as ring-strain adjustable supports for iron and cobalt catalysts in ethylene oligo-/polymerization

Z Wang, GA Solan, W Zhang, WH Sun - Coordination Chemistry Reviews, 2018 - Elsevier
Recent progress in the application of homogeneous iron and cobalt catalysts in ethylene
oligo-/polymerization is reviewed with particular emphasis placed on the tuning of catalyst …

Photoinduced iron-catalyzed C–H alkylation of polyolefins

Z Zhang, Y Zhang, R Zeng - Chemical Science, 2023 - pubs.rsc.org
Chemically introducing diverse polar groups into polyolefins via carbon–hydrogen bond
alkylation with polar olefins is of substantial value in the synthesis of next-generation …

Materials from waste plastics for CO 2 capture and utilisation

JYQ Teo, A Ong, TTY Tan, X Li, XJ Loh, JYC Lim - Green Chemistry, 2022 - pubs.rsc.org
Anthropogenic activities have resulted in a sustained increase in atmospheric CO2 levels
over the past 200 years. To mitigate this, materials capable of capturing or chemically …

Organocatalytic aerobic oxidative degradation of polystyrene to aromatic acids

A Ong, JYQ Teo, Z Feng, TTY Tan… - … Sustainable Chemistry & …, 2023 - ACS Publications
Polystyrenes are among the most prevalent commercial plastics produced worldwide, but
their end-of-life treatment remains highly suboptimal today. Although currently only in their …