Discrete cationic complexes for ring-opening polymerization catalysis of cyclic esters and epoxides

Y Sarazin, JF Carpentier - Chemical reviews, 2015 - ACS Publications
1.1 Background Interest in ring-opening polymerization (ROP) reactions has gained
tremendous momentum in the course of the past two decades.(1) While the polymerization …

Dinuclear catalysts for the ring opening polymerization of lactide

AB Kremer, P Mehrkhodavandi - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract Poly (lactic acid)(PLA) is by far the most commonly produced biodegradable
polyester. Metal-mediated ring opening polymerization of lactide is the most studied route for …

Sustainable bioplastics derived from renewable natural resources for food packaging

X Zhao, Y Wang, X Chen, X Yu, W Li, S Zhang, X Meng… - Matter, 2023 - cell.com
Food packaging is one of the leading sectors for the end use of plastics. Bioplastic is
produced from natural renewable resources such as crops, wood pulp, and herbaceous …

Toward infinitely recyclable plastics derived from renewable cyclic esters

X Tang, EYX Chen - Chem, 2019 - cell.com
Plastics, used in countless consumer products that our daily lives depend on, have become
indispensable materials essential for modern life and the global economy. At the same time …

A nanoscale MOF-based heterogeneous catalytic system for the polymerization of N-carboxyanhydrides enables direct routes toward both polypeptides and related …

Y Liu, Z Ren, N Zhang, X Yang, Q Wu, Z Cheng… - Nature …, 2023 - nature.com
Synthetic polypeptides have emerged as versatile tools in both materials science and
biomedical engineering due to their tunable properties and biodegradability. While the …

Recent progress in the application of group 1, 2 & 13 metal complexes as catalysts for the ring opening polymerization of cyclic esters

J Gao, D Zhu, W Zhang, GA Solan, Y Ma… - Inorganic Chemistry …, 2019 - pubs.rsc.org
High performance biodegradable polymers (eg, aliphatic polyesters) that can display
properties that rival polyolefins are seen as future high demand materials for a variety of …

Amphiphilic copolymers in biomedical applications: Synthesis routes and property control

F Perin, A Motta, D Maniglio - Materials Science and Engineering: C, 2021 - Elsevier
The request of new materials, matching strict requirements to be applied in precision and
patient-specific medicine, is pushing for the synthesis of more and more complex block …

Mechanism of living lactide polymerization by dinuclear indium catalysts and its impact on isoselectivity

I Yu, A Acosta-Ramirez… - Journal of the American …, 2012 - ACS Publications
A family of racemic and enantiopure indium complexes 1–11 bearing bulky chiral
diaminoaryloxy ligands, H (NNOR), were synthesized and fully characterized. Investigation …

Zwitterionic organocatalysis for ring-opening polymerization of cyclic esters

Y Xu, P Guo, Z Li, Z Liu, T Zhu, Y Wang, H Zhang… - Green …, 2024 - pubs.rsc.org
Zwitterionic catalysis is powerful in simultaneously activating electrophiles and nucleophiles
in organic transformations; however, its potential in polymerizations remains untapped …

Aluminum alkyl complexes: synthesis, structure, and application in ROP of cyclic esters

Y Wei, S Wang, S Zhou - Dalton Transactions, 2016 - pubs.rsc.org
Aluminum alkyl complexes have very useful applications as catalysts or reagents in small
molecule transformations and as cocatalysts in olefin polymerization. This short review …