Discrete cationic complexes for ring-opening polymerization catalysis of cyclic esters and epoxides
Y Sarazin, JF Carpentier - Chemical reviews, 2015 - ACS Publications
1.1 Background Interest in ring-opening polymerization (ROP) reactions has gained
tremendous momentum in the course of the past two decades.(1) While the polymerization …
tremendous momentum in the course of the past two decades.(1) While the polymerization …
Dinuclear catalysts for the ring opening polymerization of lactide
AB Kremer, P Mehrkhodavandi - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract Poly (lactic acid)(PLA) is by far the most commonly produced biodegradable
polyester. Metal-mediated ring opening polymerization of lactide is the most studied route for …
polyester. Metal-mediated ring opening polymerization of lactide is the most studied route for …
Sustainable bioplastics derived from renewable natural resources for food packaging
Food packaging is one of the leading sectors for the end use of plastics. Bioplastic is
produced from natural renewable resources such as crops, wood pulp, and herbaceous …
produced from natural renewable resources such as crops, wood pulp, and herbaceous …
Toward infinitely recyclable plastics derived from renewable cyclic esters
Plastics, used in countless consumer products that our daily lives depend on, have become
indispensable materials essential for modern life and the global economy. At the same time …
indispensable materials essential for modern life and the global economy. At the same time …
A nanoscale MOF-based heterogeneous catalytic system for the polymerization of N-carboxyanhydrides enables direct routes toward both polypeptides and related …
Y Liu, Z Ren, N Zhang, X Yang, Q Wu, Z Cheng… - Nature …, 2023 - nature.com
Synthetic polypeptides have emerged as versatile tools in both materials science and
biomedical engineering due to their tunable properties and biodegradability. While the …
biomedical engineering due to their tunable properties and biodegradability. While the …
Recent progress in the application of group 1, 2 & 13 metal complexes as catalysts for the ring opening polymerization of cyclic esters
High performance biodegradable polymers (eg, aliphatic polyesters) that can display
properties that rival polyolefins are seen as future high demand materials for a variety of …
properties that rival polyolefins are seen as future high demand materials for a variety of …
Amphiphilic copolymers in biomedical applications: Synthesis routes and property control
F Perin, A Motta, D Maniglio - Materials Science and Engineering: C, 2021 - Elsevier
The request of new materials, matching strict requirements to be applied in precision and
patient-specific medicine, is pushing for the synthesis of more and more complex block …
patient-specific medicine, is pushing for the synthesis of more and more complex block …
Mechanism of living lactide polymerization by dinuclear indium catalysts and its impact on isoselectivity
I Yu, A Acosta-Ramirez… - Journal of the American …, 2012 - ACS Publications
A family of racemic and enantiopure indium complexes 1–11 bearing bulky chiral
diaminoaryloxy ligands, H (NNOR), were synthesized and fully characterized. Investigation …
diaminoaryloxy ligands, H (NNOR), were synthesized and fully characterized. Investigation …
Zwitterionic organocatalysis for ring-opening polymerization of cyclic esters
Y Xu, P Guo, Z Li, Z Liu, T Zhu, Y Wang, H Zhang… - Green …, 2024 - pubs.rsc.org
Zwitterionic catalysis is powerful in simultaneously activating electrophiles and nucleophiles
in organic transformations; however, its potential in polymerizations remains untapped …
in organic transformations; however, its potential in polymerizations remains untapped …
Aluminum alkyl complexes: synthesis, structure, and application in ROP of cyclic esters
Y Wei, S Wang, S Zhou - Dalton Transactions, 2016 - pubs.rsc.org
Aluminum alkyl complexes have very useful applications as catalysts or reagents in small
molecule transformations and as cocatalysts in olefin polymerization. This short review …
molecule transformations and as cocatalysts in olefin polymerization. This short review …