We survey the most important kinds of structural complexity in Prussian blue analogues,
their implications for materials function, and how they might be controlled through judicious …

The coordination chemistry of transition metal hexacyanometallates is a field of continuous
advances and emerging applications. In the last three decades, relevant progress has been …

Prussian blue analogues (PBAs) are archetypes of microporous coordination
polymers/metal–organic frameworks whose versatile composition allows for diverse …

The oxygen evolution reaction (OER) is limited by the inherent linear scaling relationships of
its reaction intermediates. Manipulating the spin configuration of the water oxidation …

Octahedral tilting is key to the structure and functionality of perovskites. We present a
metastudy of published literature showing how these distortions manifest in the related …

The vast compositional space of Prussian blue analogues (PBAs), formula A x M [M′(CN)
6] y· n H2O, allows for a diverse range of functionality. Yet, the interplay between …

Jahn–Teller (JT) distorted CuII-containing compounds often display interesting structural
and functional behaviour upon compression. We use high-pressure X-ray and neutron …

To date, group 10 metal-cyanide scaffolds as promising candidates in the form of discrete
organometallic complexes or one-, two-and three-dimensional coordination polymers have …

Size reduction offers a synthetic route to tunable phase change behavior. Preparing
materials as nanoparticles causes drastic modulations to critical temperatures (T c) …

Operando synchrotron radiation-based techniques are a precious tool in battery research,
as they enable the detection of metastable intermediates and ensure characterization under …