Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis

WT Hong, M Risch, KA Stoerzinger… - Energy & …, 2015 - pubs.rsc.org
In this Review, we discuss the state-of-the-art understanding of non-precious transition metal
oxides that catalyze the oxygen reduction and evolution reactions. Understanding and …

Persistent and partially mobile oxygen vacancies in Li-rich layered oxides

PM Csernica, SS Kalirai, WE Gent, K Lim, YS Yu, Y Liu… - Nature Energy, 2021 - nature.com
Increasing the energy density of layered oxide battery electrodes is challenging as
accessing high states of delithiation often triggers voltage degradation and oxygen release …

[HTML][HTML] Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides

WE Gent, K Lim, Y Liang, Q Li, T Barnes, SJ Ahn… - Nature …, 2017 - nature.com
Lithium-rich layered transition metal oxide positive electrodes offer access to anion redox at
high potentials, thereby promising high energy densities for lithium-ion batteries. However …

Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles

J Lim, Y Li, DH Alsem, H So, SC Lee, P Bai… - Science, 2016 - science.org
The kinetics and uniformity of ion insertion reactions at the solid-liquid interface govern the
rate capability and lifetime, respectively, of electrochemical devices such as Li-ion batteries …

Determination of surface potential and electrical double-layer structure at the aqueous electrolyte-nanoparticle interface

MA Brown, Z Abbas, A Kleibert, RG Green, A Goel… - Physical Review X, 2016 - APS
The structure of the electrical double layer has been debated for well over a century, since it
mediates colloidal interactions, regulates surface structure, controls reactivity, sets …

Chemical composition mapping with nanometre resolution by soft X-ray microscopy

DA Shapiro, YS Yu, T Tyliszczak, J Cabana… - Nature …, 2014 - nature.com
X-ray microscopy is powerful in that it can probe large volumes of material at high spatial
resolution with exquisite chemical, electronic and bond orientation contrast,,,,. The …

[HTML][HTML] Surface science under reaction conditions: CO oxidation on Pt and Pd model catalysts

MA Van Spronsen, JWM Frenken… - Chemical Society …, 2017 - pubs.rsc.org
Platinum and palladium are frequently used as catalytic materials, for example for the
oxidation of CO. This is one of the most widely studied reactions in the field of surface …

Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects

BR Cuenya - Thin Solid Films, 2010 - Elsevier
Exciting new opportunities are emerging in the field of catalysis based on nanotechnology
approaches. A new understanding and mastery of catalysis could have broad societal …

Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes

Y Li, F El Gabaly, TR Ferguson, RB Smith, NC Bartelt… - Nature materials, 2014 - nature.com
Many battery electrodes contain ensembles of nanoparticles that phase-separate on (de)
intercalation. In such electrodes, the fraction of actively intercalating particles directly …