Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Ultrafast electron diffraction: Visualizing dynamic states of matter

D Filippetto, P Musumeci, RK Li, BJ Siwick… - Reviews of Modern …, 2022 - APS
Since the discovery of electron-wave duality, electron scattering instrumentation has
developed into a powerful array of techniques for revealing the atomic structure of matter …

Scalable integration of hybrid high-κ dielectric materials on two-dimensional semiconductors

Y Xu, T Liu, K Liu, Y Zhao, L Liu, P Li, A Nie, L Liu… - Nature Materials, 2023 - nature.com
Abstract Two-dimensional (2D) semiconductors are promising channel materials for next-
generation field-effect transistors (FETs). However, it remains challenging to integrate …

Tailoring water structure with high-tetrahedral-entropy for antifreezing electrolytes and energy storage at− 80° C

M Qiu, P Sun, K Han, Z Pang, J Du, J Li, J Chen… - Nature …, 2023 - nature.com
One of unsolved puzzles about water lies in how ion-water interplay affects its freezing point.
Here, we report the direct link between tetrahedral entropy and the freezing behavior of …

Eutectic electrolytes in advanced metal-ion batteries

L Geng, X Wang, K Han, P Hu, L Zhou, Y Zhao… - ACS Energy …, 2021 - ACS Publications
Metal-ion batteries (MIBs) are promising for large-scale energy storage because they can
alleviate the inherent intermittency of renewable energy. As an indispensable part of MIBs …

Visualizing Eigen/Zundel cations and their interconversion in monolayer water on metal surfaces

Y Tian, J Hong, D Cao, S You, Y Song, B Cheng… - Science, 2022 - science.org
The nature of hydrated proton on solid surfaces is of vital importance in electrochemistry,
proton channels, and hydrogen fuel cells but remains unclear because of the lack of atomic …

[HTML][HTML] The physics behind water irregularity

CQ Sun, Y Huang, X Zhang, Z Ma, B Wang - Physics Reports, 2023 - Elsevier
The notion of asymmetrical Hydrogen Bond (O: HO) Cooperativity and Polarizability (HBCP)
has enabled exploration of the core physics behind irregularities of water and ice …

Spectroscopically visualizing the evolution of hydrogen-bonding interactions

X Yi, W Chen, Y Xiao, F Liu, X Yu… - Journal of the American …, 2023 - ACS Publications
Understanding chemical bond variations is the soul of chemistry as it is essential for any
chemical process. The evolution of hydrogen bonds is one of the most fundamental and …

Self-hybridized vibrational-Mie polaritons in water droplets

A Canales, OV Kotov, B Küçüköz, TO Shegai - Physical Review Letters, 2024 - APS
We study the self-hybridization between Mie modes supported by water droplets with
stretching and bending vibrations in water molecules. Droplets with radii> 2.7 μ m are found …

Femtosecond electronic and hydrogen structural dynamics in ammonia imaged with ultrafast electron diffraction

EG Champenois, NH List, M Ware, M Britton… - Physical Review Letters, 2023 - APS
Directly imaging structural dynamics involving hydrogen atoms by ultrafast diffraction
methods is complicated by their low scattering cross sections. Here we demonstrate that …