Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …
occupy an important position. Unfortunately, no two nanoparticles from conventional …
Structural engineering toward gold nanocluster catalysis
ZJ Guan, JJ Li, F Hu, QM Wang - Angewandte Chemie, 2022 - Wiley Online Library
Atomically precise gold nanoclusters provide great opportunities to explore the relationship
between the structure and properties of nanogold catalysts. A nanocluster consists of a …
between the structure and properties of nanogold catalysts. A nanocluster consists of a …
Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …
Atomically tailored gold nanoclusters for catalytic application
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …
have significantly broadened the accessible sizes and structures. Such particles are well …
Atomically precise metal nanoclusters for catalysis
Recent efforts in nanoscience to control nanoparticles with atomic precision have met with
success in solution-phase chemistry, opening new opportunities. The products, atomically …
success in solution-phase chemistry, opening new opportunities. The products, atomically …
Optical properties and excited-state dynamics of atomically precise gold nanoclusters
Understanding the excited-state dynamics of nanomaterials is essential to their applications
in photoenergy storage and conversion. This review summarizes recent progress in the …
in photoenergy storage and conversion. This review summarizes recent progress in the …
Atomically precise metal nanoclusters meet metal-organic frameworks
Significant progress has been made in both fields of atomically precise metal nanoclusters
(NCs) and metal-organic frameworks (MOFs) in recent years. A promising direction is to …
(NCs) and metal-organic frameworks (MOFs) in recent years. A promising direction is to …
The ligand effect of atomically precise gold nanoclusters in tailoring catalytic properties
S Li, W Tian, Y Liu - Nanoscale, 2021 - pubs.rsc.org
It is well known that surface ligands are vital layers for ligand-protected Aun nanoclusters.
Improving the knowledge of the relationship between ligands and catalytic properties is a …
Improving the knowledge of the relationship between ligands and catalytic properties is a …
Activation of atom-precise clusters for catalysis
V Sudheeshkumar, KO Sulaiman, RWJ Scott - Nanoscale Advances, 2020 - pubs.rsc.org
The use of atom-precise, ligand-protected metal clusters has exceptional promise towards
the fabrication of model supported-nanoparticle heterogeneous catalysts which have …
the fabrication of model supported-nanoparticle heterogeneous catalysts which have …
AuPt bimetallic nanoalloys supported on SBA-15: A superior catalyst for quinoline selective hydrogenation in water
The structure and size of bimetallic catalysts play a crucial role in many important chemical
transformations. Controlled synthesis of bimetallic nanoparticles avoiding overgrowth and …
transformations. Controlled synthesis of bimetallic nanoparticles avoiding overgrowth and …