Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Structural engineering toward gold nanocluster catalysis

ZJ Guan, JJ Li, F Hu, QM Wang - Angewandte Chemie, 2022 - Wiley Online Library
Atomically precise gold nanoclusters provide great opportunities to explore the relationship
between the structure and properties of nanogold catalysts. A nanocluster consists of a …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Atomically tailored gold nanoclusters for catalytic application

T Higaki, Y Li, S Zhao, Q Li, S Li, XS Du… - Angewandte …, 2019 - Wiley Online Library
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …

Atomically precise metal nanoclusters for catalysis

X Du, R Jin - Acs Nano, 2019 - ACS Publications
Recent efforts in nanoscience to control nanoparticles with atomic precision have met with
success in solution-phase chemistry, opening new opportunities. The products, atomically …

Optical properties and excited-state dynamics of atomically precise gold nanoclusters

M Zhou, R Jin - Annual Review of Physical Chemistry, 2021 - annualreviews.org
Understanding the excited-state dynamics of nanomaterials is essential to their applications
in photoenergy storage and conversion. This review summarizes recent progress in the …

Atomically precise metal nanoclusters meet metal-organic frameworks

L Luo, R Jin - Iscience, 2021 - cell.com
Significant progress has been made in both fields of atomically precise metal nanoclusters
(NCs) and metal-organic frameworks (MOFs) in recent years. A promising direction is to …

The ligand effect of atomically precise gold nanoclusters in tailoring catalytic properties

S Li, W Tian, Y Liu - Nanoscale, 2021 - pubs.rsc.org
It is well known that surface ligands are vital layers for ligand-protected Aun nanoclusters.
Improving the knowledge of the relationship between ligands and catalytic properties is a …

Activation of atom-precise clusters for catalysis

V Sudheeshkumar, KO Sulaiman, RWJ Scott - Nanoscale Advances, 2020 - pubs.rsc.org
The use of atom-precise, ligand-protected metal clusters has exceptional promise towards
the fabrication of model supported-nanoparticle heterogeneous catalysts which have …

AuPt bimetallic nanoalloys supported on SBA-15: A superior catalyst for quinoline selective hydrogenation in water

J Zhao, H Yuan, G Yang, Y Liu, X Qin, Z Chen… - Nano Research, 2022 - Springer
The structure and size of bimetallic catalysts play a crucial role in many important chemical
transformations. Controlled synthesis of bimetallic nanoparticles avoiding overgrowth and …