Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals

R Cauwenbergh, V Goyal, R Maiti, K Natte… - Chemical Society …, 2022 - pubs.rsc.org
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Transition‐metal‐catalyzed carboxylation reactions with carbon dioxide

A Tortajada, F Juliá‐Hernández… - Angewandte Chemie …, 2018 - Wiley Online Library
Driven by the inherent synthetic potential of CO2 as an abundant, inexpensive and
renewable C1 chemical feedstock, the recent years have witnessed renewed interest in …

Visible-Light-Driven Catalytic Reductive Carboxylation with CO2

Z Zhang, JH Ye, T Ju, LL Liao, H Huang, YY Gui… - ACS …, 2020 - ACS Publications
Carbon dioxide (CO2) is an important C1 source for the generation of important carboxylic
acids and derivatives. Stoichiometric and catalytic carboxylation of nucleophiles, including …

Transition metal-catalyzed carboxylation of unsaturated substrates with CO2

SS Yan, Q Fu, LL Liao, GQ Sun, JH Ye, L Gong… - Coordination Chemistry …, 2018 - Elsevier
The utilization of CO 2 as a C1 building block for the synthesis of valuable chemicals is of
great importance. The transition metal-catalyzed carboxylation of unsaturated substrates …

Ligand-Controlled Regioselective Hydrocarboxylation of Styrenes with CO2 by Combining Visible Light and Nickel Catalysis

QY Meng, S Wang, GS Huff… - Journal of the American …, 2018 - ACS Publications
The ligand-controlled Markovnikov and anti-Markovnikov hydrocarboxylation of styrenes
with atmospheric pressure of CO2 at room temperature using dual visible-light-nickel …

Light‐Mediated Carboxylation Using Carbon Dioxide

Z Fan, Z Zhang, C Xi - ChemSusChem, 2020 - Wiley Online Library
Carbon dioxide is a green and sustainable one‐carbon source, which could be utilized in
the production of various fine chemicals. In recent studies, the light‐mediated carboxylation …

Development of an improved system for the carboxylation of aryl halides through mechanistic studies

DJ Charboneau, GW Brudvig, N Hazari, HMC Lant… - ACS …, 2019 - ACS Publications
The nickel-catalyzed carboxylation of organic halides or pseudohalides using carbon
dioxide is an emerging method to prepare synthetically valuable carboxylic acids. Here, we …

Übergangsmetallkatalysierte Carboxylierungen mit Kohlendioxid

A Tortajada, F Juliá‐Hernández… - Angewandte …, 2018 - Wiley Online Library
In den letzten Jahren hat das Interesse an katalytischen Reaktionen zum Einbau von CO2
als allgegenwärtigem und preisgünstigem C1‐Rohstoff in organischen Stoffen aufs Neue …

Transition Metal‐Catalyzed and Metal‐Free Cyclization Reactions of Alkynes with Nitrogen‐Containing Substrates: Synthesis of Pyrrole Derivatives

JSS Neto, G Zeni - ChemCatChem, 2020 - Wiley Online Library
This review describes the efforts in the synthesis of pyrrole derivatives using the reaction of
alkynes with nitrogen‐compounds under transition metal‐catalyzed and metal‐free …

Metal–Ligand Cooperation as Key in Formation of Dearomatized NiII–H Pincer Complexes and in Their Reactivity toward CO and CO2

D Oren, Y Diskin-Posner, L Avram, M Feller… - …, 2018 - ACS Publications
The unique synthesis and reactivity of [(RPNP*) NiH] complexes (1a, b), based on metal–
ligand cooperation (MLC), are presented (RPNP*= deprotonated PNP ligand, R= iPr, tBu) …