Ferroelectricity in molecular solids: a review of electrodynamic properties

S Tomić, M Dressel - Reports on progress in physics, 2015 - iopscience.iop.org
In conventional ferroelectrics the polarization is induced either by the relative displacement
of positive and negative ions due to a lattice distortion or by the collective alignment of …

Molecular donor–acceptor compounds as prospective organic electronics materials

S Horiuchi, T Hasegawa, Y Tokura - … of the Physical Society of Japan, 2006 - journals.jps.jp
The π-electronic functionalities of molecular donor (D)–acceptor (A) compounds have been
attracting subjects for the solid state science as well as for the prospective technological …

Chemical approach to neutral–ionic valence instability, quantum phase transition, and relaxor ferroelectricity in organic charge-transfer complexes

S Horiuchi, R Kumai, Y Okimoto, Y Tokura - Chemical physics, 2006 - Elsevier
Neutral–ionic (NI) phase transition is a reversible switching of organic charge-transfer
complexes between distinct valence states by external stimuli. This phase transformation in …

Phenomenology of the neutral-ionic valence instability in mixed stack charge-transfer crystals

M Masino, N Castagnetti, A Girlando - Crystals, 2017 - mdpi.com
Organic charge-transfer (CT) crystals constitute an important class of functional materials,
characterized by the directional charge-transfer interaction between π-electron Donor (D) …

Ionic versus electronic ferroelectricity in donor–acceptor molecular sequences

S Horiuchi, K Kobayashi, R Kumai… - Chemistry Letters, 2014 - academic.oup.com
Molecular displacement in an alternating chain of donors and acceptors triggers ferroelectric
switching of large electric polarization with a low electric field in some charge-transfer …

Static and dynamic order of cooperative multi-electron transfer

T Luty, H Cailleau, S Koshihara, E Collet… - Europhysics …, 2002 - iopscience.iop.org
We report on high correlation and ordering of multi-electron transfer at neutral-ionic
transformation in quasi–one-dimensional prototype crystal of tetrathiafulvalene-chloranil …

Optimal methods for calculation of the amount of intermolecular electron transfer

B Szefczyk, WA Sokalski, J Leszczynski - The Journal of chemical …, 2002 - pubs.aip.org
In order to determine the optimal methodology for evaluation of the magnitude of
intermolecular charge transfer, several methods have been examined: Mulliken population …

Ultrafast electron and molecular dynamics in photoinduced and electric-field-induced neutral–ionic transitions

T Morimoto, T Miyamoto, H Okamoto - Crystals, 2017 - mdpi.com
Mixed-stacked organic molecular compounds near the neutral–ionic phase boundary,
represented by tetrathiafulvalene-p-chloranil (TTF-CA), show a unique phase transition from …

Short-range ferroelectric order induced by proton transfer-mediated ionicity

M Szafrański, A Katrusiak - The Journal of Physical Chemistry B, 2004 - ACS Publications
Short-range ferroelectric order is postulated to explain unusual one-dimensional dielectric
response in ferroelectric 1, 4-diazabicyclo [2.2. 2] octane. In this pure organic salt, the polar …

Back to the structural and dynamical properties of neutral-ionic phase transitions

MBL Cointe, E Collet, B Toudic, P Czarnecki… - Crystals, 2017 - mdpi.com
Although the Neutral-Ionic transition in mixed stack charge-transfer crystals was discovered
almost forty years ago, many features of this intriguing phase transition, as well as open …