1, 1-Dihalo-1-alkenes are valuable synthetic tools in organic chemistry and serve as
interesting synthetic intermediates in a variety of non-metal-assisted chemical …

The classical form of the well-known Reformatsky reaction, introduced for the first time in
1887, 1 consists of the zincinduced formation of b-hydroxyalkanoates from ethyl a …

General reaction conditions were developed for the Pd (0)-catalyzed Suzuki− Miyaura
coupling reaction of aryl boronic acids with a simple electrophilic vinylation reagent, vinyl …

gem-Difluoroolefins with a wide range of substituents are readily synthesized from
commercially available 2, 2, 2-trifluoroethyl p-toluenesulfonate, via a pathway that comprises …

One-bond spin–spin coupling constants (SSCCs) between F and C are computed with
density functional theory (DFT). Surprisingly, M06L stands out for its striking accuracy …

In order to synthesize polycyclic aromatic hydrocarbons with nonlinear arrangements
(angular PAHs), acid‐promoted domino cyclizations of 1, 1‐difluoroalk‐1‐enes and 1, 1 …

A novel catalytic approach to (2, 2-difluorovinyl) benzenes has been developed. It was found
that hydrazones of aromatic aldehydes generated in situ could be converted to the …

α-Halo-β, β-difluorostyrenes [ArCX= CF2; X= Br, I; Ar= aryl, heteroaryl; synthesized by the Pd
(0)-catalyzed coupling reaction of the corresponding α-halo-β, β-difluoroethenylzinc …

The review is devoted to a new catalytic olefination reaction (COR) discovered by the
authors. This is the reaction between N-unsubstituted hydrazones of carbonyl compounds …

The L-proline catalyzed synthesis of α, α-difluoro homoallylic aldehydes was modified, and
these aldehydes bearing either aromatic or aliphatic groups the γ-position were obtained …