Before enzymes and templates: theory of surface metabolism

G Wächtershäuser - Microbiological reviews, 1988 - Am Soc Microbiol
Woese's three kingdoms (161-166) constitute the deepest branching of the known
biosphere. His suggestion to search for a common ancestor has led to the present …

[HTML][HTML] Groundworks for an evolutionary biochemistry: the iron-sulphur world

G Wächtershäuser - Progress in biophysics and molecular biology, 1992 - Elsevier
1. The Fundamental Alternatives 2. The First Energy Source for Life (a) Exergonic pyrite
formation (b) The requirement of redox inhibition 3. Pyrite-Surface Bonding 4. Surface …

Nuclear overhauser effect

D Neuhaus - eMagRes, 2007 - Wiley Online Library
The nuclear Overhauser effect (NOE) is defined as the change in intensity of one NMR
resonance that occurs when another is saturated. It results from dipole–dipole cross …

Activated acetic acid by carbon fixation on (Fe, Ni) S under primordial conditions

C Huber, G Wachtershauser - Science, 1997 - science.org
In experiments modeling the reactions of the reductive acetyl–coenzyme A pathway at
hydrothermal temperatures, it was found that an aqueous slurry of coprecipitated NiS and …

Crystal structure of methyl-coenzyme M reductase: the key enzyme of biological methane formation

U Ermler, W Grabarse, S Shima, M Goubeaud… - Science, 1997 - science.org
Methyl–coenzyme M reductase (MCR), the enzyme responsible for the microbial formation
of methane, is a 300-kilodalton protein organized as a hexamer in an α2β2γ2 arrangement …

Tetrapyrroles: the pigments of life

AR Battersby - Natural product reports, 2000 - pubs.rsc.org
Tetrapyrroles: the pigments of life - Natural Product Reports (RSC Publishing) DOI:10.1039/
B002635M Royal Society of Chemistry View PDF VersionPrevious ArticleNext Article DOI: 10.1039 …

Denitrifying bacteria anaerobically oxidize methane in the absence of Archaea

KF Ettwig, S Shima… - Environmental …, 2008 - Wiley Online Library
Recently, a microbial consortium was shown to couple the anaerobic oxidation of methane
to denitrification, predominantly in the form of nitrite reduction to dinitrogen gas. This …

[HTML][HTML] Chlorophylls, symmetry, chirality, and photosynthesis

MO Senge, AA Ryan, KA Letchford, SA MacGowan… - Symmetry, 2014 - mdpi.com
Chlorophylls are a fundamental class of tetrapyrroles and function as the central reaction
center, accessory and photoprotective pigments in photosynthesis. Their unique individual …

The key nickel enzyme of methanogenesis catalyses the anaerobic oxidation of methane

S Scheller, M Goenrich, R Boecher, RK Thauer, B Jaun - Nature, 2010 - nature.com
Large amounts (estimates range from 70 Tg per year to 300 Tg per year) of the potent
greenhouse gas methane are oxidized to carbon dioxide in marine sediments by …

Conformational control of cofactors in nature–the influence of protein-induced macrocycle distortion on the biological function of tetrapyrroles

MO Senge, SA MacGowan, JM O'Brien - Chemical Communications, 2015 - pubs.rsc.org
Tetrapyrrole-containing proteins are one of the most fundamental classes of enzymes in
nature and it remains an open question to give a chemical rationale for the multitude of …