We found that chiral 5-pyrimidyl alkanols are highly enantioselective asymmetric
autocatalysts forthe addition of i-Pr 2 Zn to the corresponding aldehyde. Asymmetric …

The main goal of the present review is to collect in a unified framework the deterministic and
stochastic models of emergence and amplification of chirality by mechanisms such as …

An enantiomerically enriched pyrimidyl alkanol with either S or R configurations was
obtained stochastically from the reaction between pyrimidine‐5‐carbaldehyde and …

Enantioselective synthesis induced by tetrathia-[7]-helicenes in conjunction with asymmetric
autocatalysis - ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books …

A continuous time discrete state stochastic kinetic approach is used to study various chiral
autocatalytic models in which the possibility of total asymmetric synthesis arises. It is shown …

A kinetic model of spontaneous amplification of enantiomeric excess in the autocatalytic
addition of diisopropylzinc to prochiral pyrimidine carbaldehydes is extended by a negative …

Enantioselective synthesis has been achieved using chiral compounds arising from mono-
and dideuterated methyl groups as chiral inducers in conjunction with asymmetric …

The origin of homochirality of organic compounds such as L-amino acids and D-sugars have
intrigued many scientists, and several hypotheses regarding its homochirality have been …

Asymmetric autocatalysis of 2-alkynyl-5-pyrimidyl alkanol is employed as a chiral sensor of
20 amino acids. Asymmetric autocatalysis using amino acids as chiral initiators gave …

Natural-abundance isotopic substitution in isotopically prochiral groups of otherwise achiral
molecules can provide stochastically formed enantiomeric excesses which exceed the …