Electrophotocatalysis for Organic Synthesis

MC Lamb, KA Steiniger, LK Trigoura, J Wu… - Chemical …, 2024 - ACS Publications
Electrocatalysis and photocatalysis have been the focus of extensive research efforts in
organic synthesis in recent decades, and these powerful strategies have provided a wealth …

Challenges and Future Perspectives in Photocatalysis: Conclusions from an Interdisciplinary Workshop

SB Beil, S Bonnet, C Casadevall, RJ Detz… - JACS Au, 2024 - ACS Publications
Photocatalysis is a versatile and rapidly developing field with applications spanning artificial
photosynthesis, photo-biocatalysis, photoredox catalysis in solution or supramolecular …

Electrophotocatalytic hydrogenation of imines and reductive functionalization of aryl halides

WJ Kang, Y Zhang, B Li, H Guo - Nature Communications, 2024 - nature.com
The open-shell catalytically active species, like radical cations or radical anions, generated
by one-electron transfer of precatalysts are widely used in energy-consuming redox …

Dicationic Acridinium/Carbene Hybrids as Strongly Oxidizing Photocatalysts

SC Sau, M Schmitz, C Burdenski… - Journal of the …, 2024 - ACS Publications
A new design concept for organic, strongly oxidizing photocatalysts is described based upon
dicationic acridinium/carbene hybrids. A highly modular synthesis of such hybrids is …

Photoelectrochemical Iron-Catalyzed C(sp3)–H Borylation of Alkanes in a Position-Selective Manner

W Wei, B Wang, SL Homölle, J Zhu, Y Li… - CCS …, 2024 - chinesechemsoc.org
Catalytic C–H borylation is of prime topical importance, since easily available feedstock
chemicals can thereby be transformed into valuable transient functional groups in the …

Applications of Electrophotocatalysis in C− H Functionalization of Organic Molecules

S Andrejčák, M Májek - Chemistry–A European Journal, 2024 - Wiley Online Library
Electrophotocatalysis (EPC) has evolved as a new scientific discipline around the boundary
of highly active fields: electrochemistry and photocatalysis. EPC allows us to combine the …

Electrophotoredox cerium-catalyzed decarboxylative radical cyclization cascade for the synthesis of alkylated benzimidazo-fused isoquinolinones

M Wang, D Wang, K Xu, C Zeng - Catalysis Science & Technology, 2024 - pubs.rsc.org
We report here an electrophotoredox cerium-catalyzed ligand-to-metal-charge-transfer
(LMCT) strategy to incorporate a broad range of primary, secondary and tertiary carboxylic …

Molecular Electro (Photo) Catalysis: Triarylamine and Triarylimidazole Derivatives Mediated Oxidation Systems in Organic Electrosynthesis

S Liu, L Ma, F Hao, W Gao, B Li, S Liu… - Advanced Synthesis …, 2024 - Wiley Online Library
Organic electrosynthesis has become a green, efficient and sustainable alternative to
traditional organic transformation for the redox reactions. In this connection, indirect …

Structure–property–function relationships of stabilized and persistent C-and N-based triaryl radicals

A Vasiļevska, T Slanina - Chemical Communications, 2024 - pubs.rsc.org
Structurally similar C-and N-based triaryl radicals are among the most commonly used
structural motifs in stable, open-shell, organic molecules. The application of such species is …

Integration of N-Aryl Phenoxazine Photosensitizers and Nickel Catalysts in Polymer Supports Enhances Photocatalytic Organic Transformations

C Zhu, YX Li, CH Liu, HP Cong, YY Zhu, W Lin - ACS Catalysis, 2024 - ACS Publications
Enhancing the catalytic activity of photosensitizers is critical for photocatalysis, especially in
dual catalytic systems. We present the integration of N-aryl phenoxazine photosensitizers …