Conspectus Recently, alkene dicarbofunctionalization, ie, the powerful organic synthesis
method of alkene difunctionalization with two carbon sources, emerged as a formidable …

The catalytic dicarbofunctionalization of unsaturated π bonds represents a powerful platform
for the rapid construction of complex motifs. Despite remarkable progress, novel and efficient …

1, 2-Dicarbofunctionalization of alkenes has emerged as an efficient synthetic strategy for
preparing substituted molecules by coupling readily available alkenes with electrophiles …

Advances in nickel-catalyzed cross-coupling reactions have expanded the chemical space
of accessible structures and enabled new synthetic disconnections. The unique properties of …

Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a
powerful tool for forging two C–C bonds in a single reaction. Building upon the powerful …

An asymmetric three-component carbosulfonylation of alkenes is presented here. The
reaction, involving the simultaneous formation of a C–C and a C–S bond across the π …

Alkene dicarbofunctionalizations enable the streamlined construction of aliphatic structures
and have thus been the subject of intense research efforts. Despite significant progress …

Electrochemistry grants direct access to reactive intermediates (radicals and ions) in a
controlled fashion toward selective organic transformations. This feature has been …

A visible-light-promoted photoredox/nickel protocol for the enantioselective three-
component carboarylation of alkenes with tertiary and secondary alkyltrifluoroborates and …

Alkenes, ethers, and alcohols account for a significant percentage of bulk reagents available
to the chemistry community. The petrochemical, pharmaceutical, and agrochemical …