Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Advanced materials by atom transfer radical polymerization

K Matyjaszewski - Advanced Materials, 2018 - Wiley Online Library
Atom transfer radical polymerization (ATRP) has been successfully employed for the
preparation of various advanced materials with controlled architecture. New catalysts with …

Organocatalyzed atom transfer radical polymerization driven by visible light

JC Theriot, CH Lim, H Yang, MD Ryan, CB Musgrave… - Science, 2016 - science.org
Atom transfer radical polymerization (ATRP) has become one of the most implemented
methods for polymer synthesis, owing to impressive control over polymer composition and …

Atom transfer radical polymerization: billion times more active catalysts and new initiation systems

TG Ribelli, F Lorandi, M Fantin… - Macromolecular rapid …, 2019 - Wiley Online Library
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

Macromolecular engineering by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014 - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …

Sequence-controlled polymers

JF Lutz, M Ouchi, DR Liu, M Sawamoto - Science, 2013 - science.org
Background During the last few decades, progress has been made in manipulating the
architecture of synthetic polymer materials. However, the primary structure—that is, the …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Mechanism of photoinduced metal-free atom transfer radical polymerization: experimental and computational studies

X Pan, C Fang, M Fantin, N Malhotra… - Journal of the …, 2016 - ACS Publications
Photoinduced metal-free atom transfer radical polymerization (ATRP) of methyl methacrylate
was investigated using several phenothiazine derivatives and other related compounds as …