Abstract The TpMe2Ir moiety has proven to easily promote the formal oxidative addition
reactions of unsaturated molecules, with or without concomitant formation of carbon–carbon …

We have synthesized a new type of metallaaromatic complexes, namely the hydride-β-
iridanaphthalenes TpMe2 r (H)[C (CH2R′)-C6H4-oC (R) C (R)](benzo-3-H, CH2R′), by …

This is a review of papers published in the year 2010 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon–transition metal double or triple bond.

Cyclometalation reactions are usually defined as the reactions of metal compounds with
conventional substrates, such as benzylamines and 2-phenylpyridines. In contrast …

The fully CO2Me substituted aquo-iridacyclopentadiene 1 reacts with a variety of aromatic
aldehydes, at 90–120° C, with the formation of bicyclic Fischer-type carbenes, generated by …

Trispyrazolylborate complexes of rhodium and iridium have been extensively investigated
over the past 3 decades with special attention to their ability to activate C single bond H …

Reaction of the dimeric species [Cp* IrCl 2] 2 with terminal alkynes containing a conjugated
carbonyl group results in C–C bond formation between two or three alkyne molecules …

-Proyecto CONACyT CB-2013 (223800). Titulado: Síntesis de compuestos organometálicos
de iridio, con ligantes polidentados, del tipo TpMe2Ir (C2H4) 2, y TpMe2Ir (Ph) 2N2, TpMe2Ir …

There are two applications for cyclometalation reactions and five-membered ring products
for synthetic purposes. The first is synthesis of five-membered ring products by …