A Co3O4-activated chlorite (Co3O4/chlorite) process was developed to enable the
simultaneous generation of high-valent cobalt species [Co (IV)] and ClO2 for efficient …

Ruthenium and osmium complexes are playing important roles in stoichiometric and
catalytic oxidation reactions to achieve unique chemical conversion of inorganic and organic …

The novel nonradical Fenton-like oxidation based on high-valent cobalt-oxo [Co IV double
bondO] species is a promising candidate for selectively removing emerging organic …

Cobalt oxides are recognized as one of the most efficient earth-abundant catalysts for
challenging oxidation chemistry, with substrates ranging from water to organic compounds …

C–H activation in alkanes poses a major challenge in chemistry due to the inert character of
this bond, manifesting the necessity of improved catalysts. Although various metal–oxo …

Synthetic complexes provide useful models to study the interplay between the structure and
spectroscopy of the different S n-state intermediates of the oxygen-evolving complex (OEC) …

Mechanisms combining organic radicals and metallic intermediates hold strong potential in
homogeneous catalysis. Such activation modes require careful optimization of two …

The deployment of metalloclusters in applications such as catalysis and materials synthesis
requires robust methods for site-differentiation: the conversion of clusters with symmetric …