Water-Soluble Mo3S4 Clusters Bearing Hydroxypropyl Diphosphine Ligands: Synthesis, Crystal Structure, Aqueous Speciation, and Kinetics of Substitution …
MG Basallote, MJ Fernandez-Trujillo… - Inorganic …, 2012 - ACS Publications
The [Mo3S4Cl3 (dhprpe) 3]+(1+) cluster cation has been prepared by reaction between
Mo3S4Cl4 (PPh3) 3 (solvent) 2 and the water-soluble 1, 2-bis (bis (hydroxypropyl) …
Mo3S4Cl4 (PPh3) 3 (solvent) 2 and the water-soluble 1, 2-bis (bis (hydroxypropyl) …
Synthesis and Structure of Trinuclear W3S4 Clusters Bearing Aminophosphine Ligands and Their Reactivity toward Halides and Pseudohalides
TF Beltran, JA Pino-Chamorro… - Inorganic …, 2015 - ACS Publications
The aminophosphine ligand (2-aminoethyl) diphenylphosphine (edpp) has been
coordinated to the W3 (μ-S)(μ-S) 3 cluster unit to afford trimetallic complex [W3S4Br3 (edpp) …
coordinated to the W3 (μ-S)(μ-S) 3 cluster unit to afford trimetallic complex [W3S4Br3 (edpp) …
Kinetics Aspects of the Reversible Assembly of Copper in Heterometallic Mo3CuS4 Clusters with 4,4′-Di-tert-butyl-2,2′-bipyridine
JA Pino-Chamorro, YA Laricheva, E Guillamon… - Inorganic …, 2016 - ACS Publications
Treatment of the triangular [Mo3S4Cl3 (dbbpy) 3] Cl cluster ([1] Cl) with CuCl produces a
novel tetrametallic cuboidal cluster [Mo3 (CuCl) S4Cl3 (dbbpy) 3][CuCl2]([2][CuCl2]), whose …
novel tetrametallic cuboidal cluster [Mo3 (CuCl) S4Cl3 (dbbpy) 3][CuCl2]([2][CuCl2]), whose …
Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2, 2′-bipyridine type ligands
YA Laricheva, AL Gushchin, PA Abramov, MN Sokolov - Polyhedron, 2018 - Elsevier
New cuboidal cluster complexes of general formula [Mo 3 S 4 (M′ X) Cl 3 L 3] 0/+(M′= Ni
0, Pd 0; L= dnbpy–4, 4′-dinonyl-2, 2′-bipyridine or dbbpy–4, 4′-di-tert-butyl-2, 2 …
0, Pd 0; L= dnbpy–4, 4′-dinonyl-2, 2′-bipyridine or dbbpy–4, 4′-di-tert-butyl-2, 2 …
Influence of the Ligand Alkyl Chain Length on the Solubility, Aqueous Speciation, and Kinetics of Substitution Reactions of Water-Soluble M3S4 (M = Mo, W) Clusters …
Water-soluble [M3S4X3 (dhbupe) 3]+ diphosphino complexes (dhbupe= 1, 2-bis (bis
(hydroxybutyl) phosphino) ethane), 1+(M= Mo, X= Cl) and 2+(M= W; X= Br), have been …
(hydroxybutyl) phosphino) ethane), 1+(M= Mo, X= Cl) and 2+(M= W; X= Br), have been …
Formation of [M + 15]+ ions from aromatic aldehydes by use of methanol: in‐source aldolization reaction in electrospray ionization mass spectrometry
Unexpected [M+ 15]+ ions were formed during the analysis of aromatic aldehydes by use of
methanol in positive‐ion electrospray ionization mass spectrometry. Aromatic aldehydes …
methanol in positive‐ion electrospray ionization mass spectrometry. Aromatic aldehydes …
A DFT and TD‐DFT Approach to the Understanding of Statistical Kinetics in Substitution Reactions of M3Q4 (M=Mo, W; Q=S, Se) Cuboidal Clusters
AG Algarra, MJ Fernández‐Trujillo… - … –A European Journal, 2012 - Wiley Online Library
For many years it has been known that the nine water molecules in [M3Q4 (H2O) 9] 4+
cuboidal clusters (M= Mo, W; Q= S, Se) can be replaced by entering ligands, such as …
cuboidal clusters (M= Mo, W; Q= S, Se) can be replaced by entering ligands, such as …
The Role of Solvent on the Mechanism of Proton Transfer to Hydride Complexes: The Case of the [W3PdS4H3(dmpe)3(CO)]+ Cubane Cluster
The kinetics of reaction of the [W3PdS4H3 (dmpe) 3 (CO)]+ hydride cluster (1+) with HCl has
been measured in dichloromethane, and a second‐order dependence with respect to the …
been measured in dichloromethane, and a second‐order dependence with respect to the …
Kinetic and DFT Studies on the Mechanism of C–S Bond Formation by Alkyne Addition to the [Mo3S4(H2O)9]4+ Cluster
JÁ Pino-Chamorro, AG Algarra… - Inorganic …, 2013 - ACS Publications
Reaction of [Mo3 (μ3-S)(μ-S) 3] clusters with alkynes usually leads to formation of two C–S
bonds between the alkyne and two of the bridging sulfides. The resulting compounds …
bonds between the alkyne and two of the bridging sulfides. The resulting compounds …
Tungsten and molybdenum incomplete cuboidal clusters; kinetico-mechanistic studies and association in dimers
R Hernandez-Molina, A Gushchin… - Dalton …, 2013 - pubs.rsc.org
New triangular Mo (IV) and W (IV) incomplete cuboidal cluster complexes containing three
η2-diethyldithiophosphates (dtp, one per metal centre) and a η2 (μ)-AcO or η2 (μ)-dtp ligand …
η2-diethyldithiophosphates (dtp, one per metal centre) and a η2 (μ)-AcO or η2 (μ)-dtp ligand …