C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes
nowadays allow chemists to easily access these strained rings with high diastereo-and …

Efficient difunctionalization of alkenes allows the rapid construction of molecular complexity
from simple building blocks in organic synthesis. We present herein a nickel-catalyzed …

Most of the efforts of organic chemists have been directed to the development of creative
strategies to build carbon–carbon and carbon–heteroatom bonds in a predictable and …

A radical solution: A Bu 4 NI/tert‐butyl hydroperoxide (TBHP) catalyzed synthesis of amides
through a cross‐coupling reaction between acyl and aminyl radicals is described. This …

Methylene-and alkylidenecyclopropanes (MCPs and ACPs, 1, Figure 1) and-cyclobutanes
(MCBs and ACBs, 2, Figure 1) are highly strained molecules, but at the same time most of …

The Buchwald–Hartwig C–N coupling reaction has been ranked as one of the 20 most
frequently used reactions in medicinal chemistry. Owing to its much lower cost and higher …

In this report, we present a photoredox/cobalt dual catalytic system for the synthesis of
distally unsaturated ketones. Upon a cooperative utilization of an organo photoredox …

By exploring a new mode of nickel‐catalyzed cross‐coupling, a method to directly transform
both aromatic and aliphatic aldehydes into either esters or amides has been developed. The …

When more complex system leads to simpler reactivity profile; the ring‐opening of strained
three‐membered rings such as methylene‐and alkylidenecyclopropanes generally lead to …