3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations

R Trammell, K Rajabimoghadam… - Chemical …, 2019 - ACS Publications
Copper is one of the most abundant and less toxic transition metals. Nature takes advantage
of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase …

Recent insights into lytic polysaccharide monooxygenases (LPMOs)

T Tandrup, KEH Frandsen, KS Johansen… - Biochemical Society …, 2018 - portlandpress.com
Lytic polysaccharide monooxygenases (LPMOs) are copper enzymes discovered within the
last 10 years. By degrading recalcitrant substrates oxidatively, these enzymes are major …

Homogeneous oxidative transformations mediated by copper catalyst systems

L Marais, HCM Vosloo, AJ Swarts - Coordination Chemistry Reviews, 2021 - Elsevier
Oxidative transformations involve the conversion of organic substrates, through various
processes to obtain oxygenates such as alcohols, phenolic and carbonyl compounds which …

Artificial photosynthesis for production of ATP, NAD (P) H, and hydrogen peroxide

S Fukuzumi, YM Lee, W Nam - ChemPhotoChem, 2018 - Wiley Online Library
The initial product of photosynthesis is NADPH (dihydronicotinamide adenine dinucleotide
phosphate), which is produced from the oxidized form (NADP+) by reduction with two …

Structural Elucidation, Aggregation, and Dynamic Behaviour of N,N,N,N‐Copper(I) Schiff Base Complexes in Solid and in Solution: A Combined NMR, X‐ray …

I Gerz, SAV Jannuzzi, KT Hylland… - European Journal of …, 2021 - Wiley Online Library
A series of Cu (I) complexes of bidentate or tetradentate Schiff base ligands bearing either 1‐
H‐imidazole or pyridine moieties were synthesized. The complexes were studied by a …

Transition Metal‐Catalyzed C− H Oxidation of Saturated Hydrocarbons with Molecular Oxygen

N Komiya, SI Murahashi - The Chemical Record, 2021 - Wiley Online Library
The C− H oxidation of saturated hydrocarbons to the corresponding alcohols and ketones
can be performed efficiently at room temperature with molecular oxygen (1 atm) in the …

Cu-catalyzed oxidation of indoles to isatins

J Luo, Y Zhao, X Xu, J Zheng, H Liang - Tetrahedron Letters, 2017 - Elsevier
The first example of Cu-catalyzed oxidation of indoles to isatin derivatives by the use of
cheap aqueous tert-butyl peroxide as an oxidant was developed. This methodology is …

Cycloalkane Oxidation Catalyzed by Copper‐based Catalysts with H2O2 under Mild Conditions

J Chimlert, P Suktanarak, N Plainpan… - …, 2023 - Wiley Online Library
Copper‐catalyzed cycloalkane oxidation using H2O2 as an oxidant was investigated under
mild conditions. The copper catalysts studied in this work ranged from commercially …

Hydrocarbon Oxidation Depth: H2O2/Cu2Cl4·2DMG/CH3CN System

IY Shchapin, AI Nekhaev, DN Ramazanov, M Al-Yusufi… - Catalysts, 2022 - mdpi.com
The oxidation of hydrocarbons of different structures under the same conditions is an
important stage in the study of the chemical properties of both the hydrocarbons themselves …