Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase

ST Stripp, BR Duffus, V Fourmond, C Léger… - Chemical …, 2022 - ACS Publications
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

AM Appel, JE Bercaw, AB Bocarsly, H Dobbek… - Chemical …, 2013 - ACS Publications
Two major energy-related problems confront the world in the next 50 years. First, increased
worldwide competition for gradually depleting fossil fuel reserves (derived from past …

[HTML][HTML] Metalloproteins containing cytochrome, iron–sulfur, or copper redox centers

J Liu, S Chakraborty, P Hosseinzadeh, Y Yu… - Chemical …, 2014 - ACS Publications
Redox reactions play important roles in almost all biological processes, including
photosynthesis and respiration, which are two essential energy processes that sustain all life …

State of the art and perspectives in catalytic processes for CO2 conversion into chemicals and fuels: The distinctive contribution of chemical catalysis and …

M Aresta, A Dibenedetto, E Quaranta - Journal of Catalysis, 2016 - Elsevier
The need to reduce the emission of carbon dioxide into the atmosphere is pushing toward
the use of “renewable carbon”, so to avoid as much as possible burning “fossil carbon”. It …

The mononuclear molybdenum enzymes

R Hille, J Hall, P Basu - Chemical reviews, 2014 - ACS Publications
Molybdenum is the only second-row transition metal required by most living organisms, and
is nearly universally distributed in biology. Enzymes containing molybdenum in their active …

Membrane-anchored HDCR nanowires drive hydrogen-powered CO2 fixation

HM Dietrich, RD Righetto, A Kumar, W Wietrzynski… - Nature, 2022 - nature.com
Filamentous enzymes have been found in all domains of life, but the advantage of
filamentation is often elusive. Some anaerobic, autotrophic bacteria have an unusual …

Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2 nd sphere interactions in catalysis

S Amanullah, P Saha, A Nayek, ME Ahmed… - Chemical Society …, 2021 - pubs.rsc.org
Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …

A post-genomic view of the ecophysiology, catabolism and biotechnological relevance of sulphate-reducing prokaryotes

R Rabus, SS Venceslau, L Wöhlbrand… - Advances in microbial …, 2015 - Elsevier
Dissimilatory sulphate reduction is the unifying and defining trait of sulphate-reducing
prokaryotes (SRP). In their predominant habitats, sulphate-rich marine sediments, SRP have …

Sulfur and selenium: the role of oxidation state in protein structure and function

C Jacob, GI Giles, NM Giles… - Angewandte Chemie …, 2003 - Wiley Online Library
Sulfur and selenium occur in proteins as constituents of the amino acids cysteine,
methionine, selenocysteine, and selenomethionine. Recent research underscores that these …

Reversible interconversion of carbon dioxide and formate by an electroactive enzyme

T Reda, CM Plugge, NJ Abram… - Proceedings of the …, 2008 - National Acad Sciences
Carbon dioxide (CO2) is a kinetically and thermodynamically stable molecule. It is easily
formed by the oxidation of organic molecules, during combustion or respiration, but is …