Metallodithiolates as ligands in coordination, bioinorganic, and organometallic chemistry
JA Denny, MY Darensbourg - Chemical Reviews, 2015 - ACS Publications
In a series of notable manuscripts in the early 1960s, Daryle H. Busch and co-workers
described reactions of coordinated ligands, particularly choosing mercaptoamines (NS) to …
described reactions of coordinated ligands, particularly choosing mercaptoamines (NS) to …
Structural and functional models related to the nickel hydrogenases
In this review a historic overview is given of the biomimetic models synthesised since the
presence of nickel in hydrogenases was first reported in 1981. The crystal structure of the …
presence of nickel in hydrogenases was first reported in 1981. The crystal structure of the …
Hemilabile Bridging Thiolates as Proton Shuttles in Bioinspired H2 Production Electrocatalysts
S Ding, P Ghosh, AM Lunsford, N Wang… - Journal of the …, 2016 - ACS Publications
Synthetic analogues and computationally assisted structure–function analyses have been
used to explore the features that control proton–electron and proton–hydride coupling in …
used to explore the features that control proton–electron and proton–hydride coupling in …
Spectroscopic and computational studies of Ni superoxide dismutase: electronic structure contributions to enzymatic function
AT Fiedler, PA Bryngelson, MJ Maroney… - Journal of the …, 2005 - ACS Publications
Ni-containing superoxide dismutase (NiSOD) is the most recently discovered member of the
class of metalloenzymes that detoxify the superoxide radical in aerobic organisms. In this …
class of metalloenzymes that detoxify the superoxide radical in aerobic organisms. In this …
Novel hierarchical NiO nanoflowers exhibiting intrinsic superoxide dismutase-like activity
J Mu, X Zhao, J Li, EC Yang, XJ Zhao - Journal of Materials Chemistry …, 2016 - pubs.rsc.org
Novel hierarchical NiO nanoflowers assembled by ultrathin nanoflakes were found to exhibit
intrinsic superoxide dismutase-like activity for the first time. Arising from the unique flower …
intrinsic superoxide dismutase-like activity for the first time. Arising from the unique flower …
A nickel superoxide dismutase maquette that reproduces the spectroscopic and functional properties of the metalloenzyme
J Shearer, LM Long - Inorganic chemistry, 2006 - ACS Publications
Described herein is a nickel superoxide dismutase (NiSOD) maquette ([Ni (SODM1)]) based
on the first 12 residues from the N-terminal sequence of Streptomyces coelicolor NiSOD …
on the first 12 residues from the N-terminal sequence of Streptomyces coelicolor NiSOD …
Aggregation of octahedral thiolato complexes by forming sulfur-bridged structures with transition metal ions
T Konno - Bulletin of the Chemical Society of Japan, 2004 - academic.oup.com
The main developments in rational construction of chiral metallo-aggregates based on
octahedral metal complexes with 2-aminoethanethiolate (aet) or l-cysteinate (l-cys), as well …
octahedral metal complexes with 2-aminoethanethiolate (aet) or l-cysteinate (l-cys), as well …
Characterization of Steric and Electronic Properties of NiN2S2 Complexes as S-Donor Metallodithiolate Ligands
MV Rampersad, SP Jeffery, ML Golden… - Journal of the …, 2005 - ACS Publications
The physical properties and structures of a series of six complexes of the type (NiN2S2) W
(CO) 4 have been used to establish electronic and steric parameters for square planar …
(CO) 4 have been used to establish electronic and steric parameters for square planar …
Modeling Nickel Hydrogenases: Synthesis and Structure of a Distorted Octahedral Complex with an Unprecedented [NiS4H2] Core
HM Alvarez, M Krawiec, BT Donovan-Merkert… - Inorganic …, 2001 - ACS Publications
The homoleptic nickel (II) bis (mercaptoimidazolyl) borate complex Ni (BmMe) 2 has been
readily synthesized in good yield and characterized by a combination of analytical and …
readily synthesized in good yield and characterized by a combination of analytical and …