[HTML][HTML] Earth-abundant 3d transition metal catalysts for hydroalkoxylation and hydroamination of unactivated alkenes

L Rocard, D Chen, A Stadler, H Zhang, R Gil… - Catalysts, 2021 - mdpi.com
This review summarizes the most noteworthy achievements in the field of C–O and C–N
bond formation by hydroalkoxylation and hydroamination reactions on unactivated alkenes …

Access to Azepino-Annulated Benzo[c]carbazoles Enabled by Gold-Catalyzed Hydroarylation of Alkynylindoles and Subsequent Oxidative Cyclization

JM Yang, ML Yao, JC Li, JK Liu, B Wu - Organic Letters, 2022 - ACS Publications
Herein, we report a facile and efficient synthetic method to construct azepino [1, 2-a] indoles
through a novel gold (I)-catalyzed intramolecular hydroarylation of alkynylindoles. A wide …

Visible-light-induced synthesis of N-disulfanyl indoles, pyrroles or carbazoles via the construction of stable S–S–N bonds

T Lao, J Chen, X Zhou, Z Zhang, G Cao, Z Su… - Chemical …, 2023 - pubs.rsc.org
A simple and efficient visible-light-induced approach for the formation of stable S–S–N
bonds has been developed. Through these photocatalytic reactions, a series of N-disulfanyl …

Substrate-Controlled Regiodivergent Synthesis of Fluoroacylated Carbazoles via Friedel–Crafts Acylation

XT Wu, EK Xiao, F Ma, J Yin, J Wang… - The Journal of …, 2021 - ACS Publications
A general, efficient, and substrate-controlled regiodivergent trifluoroacetylation of carbazoles
has been developed through Friedel–Crafts acylation. This strategy was applicable to a …

Synthesis and Photophysical Study of Heteropolycyclic and Carbazole Motif: Nickel-Catalyzed Chelate-Assisted Cascade C–H Activations/Annulations

N Prusty, SK Banjare, SR Mohanty, T Nanda… - Organic …, 2021 - ACS Publications
Herein, nickel-catalyzed synthesis of polyarylcarbazole through sequential C–H bond
activations has been described. Regioselective indole C2/C3 functionalization has been …

The Regioselective Functionalization Reaction of Unprotected Carbazoles with Donor–Acceptor Cyclopropanes

H Zhao, P Shen, D Sun, H Zhai… - The Journal of Organic …, 2021 - ACS Publications
The regioselective functionalization reaction of unprotected carbazoles with donor–acceptor
(D–A) cyclopropanes has been demonstrated for the first time. With Sc (OTf) 3 as Lewis acid …

Iron-catalyzed alkylation of carbazole derivatives via hydroarylation of styrenes

EK Xiao, XT Wu, F Ma, LW Miao, YJ Jiang… - Chemical …, 2021 - pubs.rsc.org
The first direct and selective 3, 6-di-alkylation of carbazoles via iron-catalyzed hydroarylation
of styrenes is demonstrated. This simple, general and efficient method could deliver a wide …

Ag/K2S2O8‐Mediated Direct Thiolation and Selenylation of Carbazoles

J Yin, P Chen, LW Miao, J Wang… - European Journal of …, 2023 - Wiley Online Library
The first direct and selective 3, 6‐di‐thiolation and 3, 6‐di‐selenylation of carbazoles using
diaryl disulfides/diselenide as the sulfur/selenium source were demonstrated. This simple …

Divergent Synthesis of Di‐ and Mono‐Alkylated Indoles via Tunable Iron‐Catalyzed Hydroarylation of Styrenes

LW Miao, P Chen, MX Hu, J Yin, H Du… - Advanced Synthesis & …, 2024 - Wiley Online Library
We report an iron‐catalyzed divergent synthesis of alkylated indoles based on precise
control of the activation sites on indoles through the selection of catalysts. Using indoles and …

Application of Nature's Chiral Pool in Environmentally Sustainable Organic Synthesis

A Gogoi, S Nongrum, G Bez - Current Organic Chemistry, 2021 - ingentaconnect.com
Recent years have witnessed a rapid development of environmentally sustainable organic
processes that can stop the eventual depletion of our eco-system with wider implications on …