[HTML][HTML] Applications of supramolecular anion recognition

N Busschaert, C Caltagirone, W Van Rossom… - Chemical …, 2015 - ACS Publications
The study of the complexation of anions, from its beginnings in the late 1960s and 1970s,(1-
3) has moved on from being an area solely of academic interest to a fundamental pillar of …

Lewis superacids: classifications, candidates, and applications

L Greb - Chemistry–A European Journal, 2018 - Wiley Online Library
Lewis acids play a major role in all areas of chemistry. For a long time, toxic, corrosive and
oxidizing SbF5 was considered as the strongest Lewis acid known. Lately, species …

Fluoride ion complexation and sensing using organoboron compounds

CR Wade, AEJ Broomsgrove, S Aldridge… - Chemical …, 2010 - ACS Publications
Fluoride is often added to drinking water and toothpaste because of its beneficial effects in
dental health. It is also administered in the treatment of osteoporosis. 1 While the beneficial …

Cocatalysts for metal-catalyzed olefin polymerization: activators, activation processes, and structure− activity relationships

EYX Chen, TJ Marks - Chemical Reviews, 2000 - ACS Publications
One of the most exciting developments in the areas of catalysis, organometallic chemistry,
and polymer science in recent years has been the intense exploration and …

Tris(ortho‐carboranyl)borane: An Isolable, Halogen‐Free, Lewis Superacid

MO Akram, JR Tidwell, JL Dutton… - Angewandte …, 2022 - Wiley Online Library
The synthesis of tris (ortho‐carboranyl) borane (BoCb3), a single site neutral Lewis
superacid, in one pot from commercially available materials is achieved. The high fluoride …

Noncoordinating anions—fact or fiction? A survey of likely candidates

I Krossing, I Raabe - Angewandte Chemie International Edition, 2004 - Wiley Online Library
Is there anything resembling a truly noncoordinating anion? Would it not be great to be able
to prepare any crazy, beautiful, or simply useful cationic species that one has in mind, or has …

Studies on the Mechanism of B(C6F5)3-Catalyzed Hydrosilation of Carbonyl Functions

DJ Parks, JM Blackwell, WE Piers - The Journal of organic …, 2000 - ACS Publications
The strong organoborane Lewis acid B (C6F5) 3 catalyzes the hydrosilation (using R3SiH)
of aromatic and aliphatic carbonyl functions at convenient rates with loadings of 1− 4%. For …

Fluoride ion recognition by chelating and cationic boranes

TW Hudnall, CW Chiu, FP Gabbaï - Accounts of chemical …, 2009 - ACS Publications
Because of the ubiquity of fluoride ions and their potential toxicity at high doses, researchers
would like to design receptors that selectively detect this anion. Fluoride is found in drinking …

Colorimetric fluoride ion sensing by boron-containing π-electron systems

S Yamaguchi, S Akiyama, K Tamao - Journal of the American …, 2001 - ACS Publications
The boron-containing π-conjugated systems, including tri (9-anthryl) borane (1) and tris [(10-
dimesitylboryl)-9-anthryl] borane (2), have been investigated as a new type of fluoride …

Nichtkoordinierende Anionen–Traum oder Wirklichkeit? Eine Übersicht zu möglichen Kandidaten

I Krossing, I Raabe - Angewandte Chemie, 2004 - Wiley Online Library
Gibt es so etwas wie ein wirklich nichtkoordinierendes Anion? Wäre es nicht großartig, jede
verrückte, schöne oder einfach nur nützliche kationische Spezies herstellen zu können, sei …