Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

The synthesis of biaryls from benzyne intermediates offers an alternative strategy to
conventional metal-catalyzed cross-coupling approaches. The concept is as old as benzyne …

The ability of the hemilabile (P, N) MeDalphos ligand to trigger oxidative addition of
iodoarenes to gold has been thoroughly studied. Competition experiments and Hammett …

Die direkte Alkenylierung der C2‐Position von Indolen, die eine leicht zu entfernende N‐
Pyrimidylgruppe tragen, mit Alkinen gelang mithilfe eines Cobalt‐Katalysators mit …

Over the past 80 years, phenyl cation intermediates have been implicated in a variety of C–
H arylation reactions. Although these examples have inspired several theoretical and …

The first example of a regioselective β-arylation of benzo [b] thiophenes and thiophenes at
room temperature with aryl iodides as coupling partners is reported. This methodology …

A convenient method for the copper (I)-catalyzed arylation of substituted imidazo [1, 2-a]
pyridine has been developed. This method is applicable to a variety of aryl electrophiles …

The efficient generation of biaryl compounds and heterocycles via the advent of the
transition-metal-free coupling reaction constitutes an important development in the last few …

Electron paramagnetic resonance and electrochemistry are used to evidence the interaction
between 1, 10-phenanthroline (Phen) and KOtBu to form the 1, 10-phenanthroline radical …

Arynes generated directly from alkyne building blocks in the presence of silver catalysts
effectively activate primary, secondary, and tertiary alkane C–H bonds. This C–H insertion …