Considering the recent rapid advancement of synthetic technologies promoted by visible
light in the last 15 years, the use of photocatalysts has been rightfully justified based on the …

In recent years, visible light-induced reactions of diazo compounds have attracted
increasing attention in organic synthesis, leading to improvement of existing reactions, as …

The development of new sustainable reactions and protocols is essential to fulfill the
growing demands of every branch of organic chemistry for greener synthetic methodologies …

Molecules displaying an α-trialkyl-α-tertiary amine motif provide access to an important and
versatile area of biologically relevant chemical space but are challenging to access through …

Herein, we report on a photochemical three-component reaction of aryldiazoacetates with
NFSI and cyclic ethers. This method allows the introduction of both fluorine and a short ether …

Density functional theory calculations were applied to study four previously published metal-
catalyzed [2, 3]-rearrangements from onium ylide intermediates, in pursuit of generalizations …

Use of sustainable energy sources in synthetic organic chemistry has become one of the
most popular research topics due to environmental pollution and global warming. In this …

DABCO mediated practical and convenient one pot method has been developed to access
sulfoxonium ylides under photoredox and metal free conditions at room temperature. The …

The photoexcitation of α-diazocarbonyl compounds produces singlet carbene intermediates
that react with nucleophilic solvent molecules to form ylides. The zwitterionic nature of these …

The Sommelet–Hauser rearrangement of X-benzylic onium ylides (X= heteroatom) is an
interesting transformation in organic synthesis. This rearrangement proceeds via …