We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …

Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …

Proudly serving the scientific community for over a century, this 97th edition of the CRC
Handbook of Chemistry and Physics is an update of a classic reference, mirroring the growth …

Many, if not most, redox reactions are coupled to proton transfers. This includes most
common sources of chemical potential energy, from the bioenergetic processes that power …

Understanding the energy it takes to build or break chemical bonds is essential for scientists
and engineers in a wide range of innovative fields, including catalysis, nanomaterials …

In this Account we have compiled a list of reliable bond energies that are based on a set of
critically evaluated experiments. A brief description of the three most important experimental …

Advanced low-temperature combustion concepts that rely on compression ignition have
placed new technological demands on the modeling of low-temperature oxidation in general …

The Earth's atmosphere offers a striking contrast with other known planets by its rich organic
composition, which results almost exclusively from the presence of life on the planet. About …

The energy difference between an uncharged species and its negative ion, referred to as an
electron affinity (EA), is an important property of atoms and molecules. Negative ions, or …

Methane oxidation at high pressures and intermediate temperatures was investigated in a
laminar flow reactor and in a rapid compression machine (RCM). The flow-reactor …