Do Ionic Liquids Slow Down in Stages?

B Borah, GR Acharya, D Grajeda… - Journal of the …, 2023 - ACS Publications
High impact recent articles have reported on the existence of a liquid–liquid (L–L) phase
transition as a function of both pressure and temperature in ionic liquids (ILs) containing the …

Room temperature ionic liquids with two symmetric ions

D Rauber, F Philippi, D Schroeder, B Morgenstern… - Chemical …, 2023 - pubs.rsc.org
Room temperature ionic liquids typically contain asymmetric organic cations. The asymmetry
is thought to enhance disorder, thereby providing an entropic counter-balance to the strong …

The Coiling Effect in Ether Ionic Liquids: Exploiting Acetate as a Probe for Transport Properties and Microenvironment Analysis

B R. de Moraes, VH Paschoal, N Keppeler… - The Journal of …, 2024 - ACS Publications
The inherently high viscosity of ionic liquids (ILs) can limit their potential applications. One
approach to address this drawback is to modify the cation side chain with ether groups …

Structure-Dependence and Mechanistic Insights into the Piezoelectric Effect in Ionic Liquids

MI Hossain, H Wang, L Adhikari, GA Baker… - The Journal of …, 2024 - ACS Publications
We reported recently that two imidazolium room-temperature ionic liquids (RTILs) exhibit the
direct piezoelectric effect (J. Phys. Chem. Lett., 2023, 14, 2731–2735). We have …

Spiers Memorial Lecture: From cold to hot, the structure and structural dynamics of dense ionic fluids

MS Emerson, R Ogbodo, CJ Margulis - Faraday discussions, 2024 - pubs.rsc.org
The structure of ionic liquids (ILs), which a decade or two ago was the subject of polite but
heated debate, is now much better understood. This has opened opportunities to ask more …

Diastereoselective Synthesis of Sulfoxide‐Functionalized N‐Heterocyclic Carbene Ruthenium Complexes: An Experimental and Computational Study

V Mechrouk, B Leforestier, W Chen… - … A European Journal, 2024 - Wiley Online Library
The synthesis of sulfoxide‐functionalized NHC ligand precursors were carried out by direct
and mild oxidation from corresponding thioether precursors with high selectivity. Using these …

Structure and dynamics in dense ionic fluids: general discussion

AP Abbott, R Atkin, MD Bala, SJ Brown… - Faraday …, 2024 - pubs.rsc.org
Claudio J. Margulis communicated in reply: To answer this question, I'd like to rst point you
to the excellent set of papers by Professor Tsuyoshi Yamaguchi1–5 that are cited in our …