Supramolecular polymerization through kinetic pathway control and living chain growth

M Wehner, F Würthner - Nature Reviews Chemistry, 2020 - nature.com
Supramolecular polymers exhibit fascinating structures, and their properties, and thus
applications, depend both on the strength and dynamics of the non-covalent bonds and on …

Cooperativity in noncovalent interactions

AS Mahadevi, GN Sastry - Chemical reviews, 2016 - ACS Publications
After conquering the atomic structure about a century ago, chemists have been largely
interested in understanding the concept of chemical bond and the formation of a molecule …

Living supramolecular polymerization realized through a biomimetic approach

S Ogi, K Sugiyasu, S Manna, S Samitsu, M Takeuchi - Nature chemistry, 2014 - nature.com
Various conventional reactions in polymer chemistry have been translated to the
supramolecular domain, yet it has remained challenging to devise living supramolecular …

Strategies to create hierarchical self-assembled structures via cooperative non-covalent interactions

C Rest, R Kandanelli, G Fernández - Chemical Society Reviews, 2015 - pubs.rsc.org
Cooperative phenomena are common processes involved in the hierarchical self-assembly
of multiple systems in nature, such as the tobacco mosaic virus and a cell's cytoskeleton …

Dipole–dipole interaction driven self-assembly of merocyanine dyes: from dimers to nanoscale objects and supramolecular materials

F Würthner - Accounts of chemical research, 2016 - ACS Publications
Conspectus π-Conjugation between heterocyclic donor (D) and acceptor (A) groups via a
polymethine chain leads to dyes with dipole moments greater than 10 D. These dipole …

Supramolecular block copolymers by seeded living polymerization of perylene bisimides

W Wagner, M Wehner, V Stepanenko… - Journal of the …, 2019 - ACS Publications
Living covalent polymerization has been a subject of intense research for many decades
and has culminated in the synthesis of a large variety of block copolymers (BCPs) with …

Near‐IR Absorbing J‐Aggregate of an Amphiphilic BF2‐Azadipyrromethene Dye by Kinetic Cooperative Self‐Assembly

Z Chen, Y Liu, W Wagner, V Stepanenko… - Angewandte …, 2017 - Wiley Online Library
A new amphiphilic BF2‐azadipyrromethene (aza‐BODIPY) dye 1 has been synthesized
using a CuI‐catalyzed “click” reaction. For this dye, two self‐assembly pathways that lead to …

Photoregulated living supramolecular polymerization established by combining energy landscapes of photoisomerization and nucleation–elongation processes

M Endo, T Fukui, SH Jung, S Yagai… - Journal of the …, 2016 - ACS Publications
The significant contribution of conventional living polymerization to polymer science assures
that living supramolecular polymerization will also lead to a variety of novel phenomena and …

Functional supramolecular aggregates based on BODIPY and aza-BODIPY dyes: control over the pathway complexity

Z Chen, Z Chen - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Boron-dipyrromethene (BODIPY) and boron-azadipyrromethene (aza-BODIPY) dyes are
attractive candidates for versatile building blocks for functional supramolecular dye …

Controlling supramolecular polymerization through multicomponent self‐assembly

P Besenius - Journal of Polymer Science Part A: Polymer …, 2017 - Wiley Online Library
The self‐assembly into supramolecular polymers is a process driven by reversible non‐
covalent interactions between monomers, and gives access to materials applications …