Decomposition process of carboxylate MOF HKUST-1 unveiled at the atomic scale level
HKUST-1 is a metal–organic framework (MOF) which plays a significant role in both
applicative and basic fields of research, thanks to its outstanding properties of adsorption …
applicative and basic fields of research, thanks to its outstanding properties of adsorption …
[HTML][HTML] Quantum phase transitions probed by EPR spectra in dimeric spin arrays with supramolecular couplings
R Calvo, RP Sartoris, OR Nascimento, M Šedivý… - Coordination Chemistry …, 2023 - Elsevier
Dimeric compounds with nearly isolated molecular units (d-units) having pairs of spins s 1
and s 2 coupled by antiferromagnetic (AFM) exchange H 0=-J 0 s 1· s 2 are non-trivial …
and s 2 coupled by antiferromagnetic (AFM) exchange H 0=-J 0 s 1· s 2 are non-trivial …
Synthesis, Structure, and Electron Paramagnetic Resonance Study of a Mixed Valent Metal–Organic Framework Containing Cu2 Paddle-Wheel Units
M Simenas, M Kobalz, M Mendt, P Eckold… - The Journal of …, 2015 - ACS Publications
We report synthesis and composite study of a novel metal–organic framework (MOF)
compound of chemical formula∞ 3 [Cu2ICu2II {H2O} 2 {(Me–trz–m ba) 2thio} 2] Cl2, where …
compound of chemical formula∞ 3 [Cu2ICu2II {H2O} 2 {(Me–trz–m ba) 2thio} 2] Cl2, where …
A 3D-coordination polymer assembled from copper propionate paddlewheels and potassium propionate 1D-polymeric rods possessing a temperature-driven single …
M Kendin, A Nikiforov, R Svetogorov… - Crystal Growth & …, 2021 - ACS Publications
An unusual strategy for the design of coordination polymers based on the combination of
large s cations and rigid d metal based secondary building units has been applied to the …
large s cations and rigid d metal based secondary building units has been applied to the …
EPR and magnetic studies of a novel copper metal organic framework (STAM-I)
HEL Mkami, MIH Mohideen, C Pal, A McKinlay… - Chemical physics …, 2012 - Elsevier
The magnetic interaction between dinuclear copper (II) in a new copper carboxylate
compound, STAM-1, has been investigated by means of EPR and SQUID measurements …
compound, STAM-1, has been investigated by means of EPR and SQUID measurements …
Unveiled the source of the structural instability of HKUST-1 powders upon mechanical compaction: Definition of a fully preserving tableting method
Metal–organic frameworks (MOFs) are getting closer to finally being used in commercial
applications. In order to maximize their packing density, mechanical strength, stability in …
applications. In order to maximize their packing density, mechanical strength, stability in …
Unusual conformation of a dinuclear paddle wheel copper (II) complex. Synthesis, structural characterization and EPR studies
V Paredes-García, RC Santana, R Madrid… - Inorganic …, 2013 - ACS Publications
An unusual and unique conformation of a paddle wheel type binuclear copper (II) complex
containing acetate and acetamido ligands,{Cu2 (μ2-O2CCH3) 4}(OCNH2CH3)(1), was …
containing acetate and acetamido ligands,{Cu2 (μ2-O2CCH3) 4}(OCNH2CH3)(1), was …
Collapse of the EPR fine structure of a one-dimensional array of weakly interacting binuclear units: A dimensional quantum phase transition
R Calvo, JE Abud, RP Sartoris, RC Santana - Physical Review B—Condensed …, 2011 - APS
Binuclear (also called dimeric) compounds with pairs of antiferromagnetically coupled spins
½, S 1 and S 2 (H ex=− J 0 S 1. S 2, with J 0< 0 for antiferromagnets), have been around …
½, S 1 and S 2 (H ex=− J 0 S 1. S 2, with J 0< 0 for antiferromagnets), have been around …
Copper 1D coordination polymers and dimers: Role of the carboxylate and the ammonium cation, crystal structures and magnetic studies
L Rigamonti, S Carlino, Y Halibi, F Demartin… - Polyhedron, 2013 - Elsevier
The 1D coordination polymers [Cu2 (syn, syn-η1: η1: μ-RCOO) 4 (anti, anti-η1: η1: μ-
RCOO)(Et3NH)] n, R= Me (1) and H (2), and the dimer [Cu2 (syn, syn-η1: η1: μ-PhCOO) 4 …
RCOO)(Et3NH)] n, R= Me (1) and H (2), and the dimer [Cu2 (syn, syn-η1: η1: μ-PhCOO) 4 …
Amphoteric reactivity of a putative Cu (ii)-m CPBA intermediate
R Kumar, A Maji, B Biswas, A Draksharapu - Dalton Transactions, 2024 - pubs.rsc.org
In copper-based enzymes, Cu-hydroperoxo/alkylperoxo species are proposed as key
intermediates for their biological activity. A vast amount of literature is available on the …
intermediates for their biological activity. A vast amount of literature is available on the …