Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system

I Senkovska, V Bon, L Abylgazina, M Mendt… - Angewandte …, 2023 - Wiley Online Library
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …

Chemistry of soft porous crystals: structural dynamics and gas adsorption properties

S Krause, N Hosono, S Kitagawa - … Chemie International Edition, 2020 - Wiley Online Library
In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by
characterizing their common structural features and the resulting structural softness and …

The chemistry and applications of flexible porous coordination polymers

N Behera, J Duan, W Jin, S Kitagawa - EnergyChem, 2021 - Elsevier
Since the late 1990s, much progress has been made in the field of the chemistry of flexible
porous coordination polymers (PCPs). Various PCP architectures have been recognized …

Elucidation of flexible metal-organic frameworks: Research progresses and recent developments

JH Lee, S Jeoung, YG Chung, HR Moon - Coordination Chemistry Reviews, 2019 - Elsevier
Flexibility is a unique property of metal-organic frameworks (MOFs) that differentiates them
from other rigid inorganic porous materials such as zeolites and porous silica. Flexible …

Frustrated flexibility in metal-organic frameworks

R Pallach, J Keupp, K Terlinden… - Nature …, 2021 - nature.com
Stimuli-responsive flexible metal-organic frameworks (MOFs) remain at the forefront of
porous materials research due to their enormous potential for various technological …

Control of structural flexibility of layered-pillared metal-organic frameworks anchored at surfaces

S Wannapaiboon, A Schneemann, I Hante, M Tu… - Nature …, 2019 - nature.com
Flexible metal-organic frameworks (MOFs) are structurally flexible, porous, crystalline solids
that show a structural transition in response to a stimulus. If MOF-based solid-state and …

Tuning the balance between dispersion and entropy to design temperature-responsive flexible metal-organic frameworks

J Wieme, K Lejaeghere, G Kresse… - Nature …, 2018 - nature.com
Temperature-responsive flexibility in metal-organic frameworks (MOFs) appeals to the
imagination. The ability to transform upon thermal stimuli while retaining a given crystalline …

Metal–organic frameworks in Germany: From synthesis to function

JD Evans, B Garai, H Reinsch, W Li, S Dissegna… - Coordination Chemistry …, 2019 - Elsevier
Metal–organic frameworks (MOFs) are constructed from a combination of inorganic and
organic units to produce materials which display high porosity, among other unique and …

One atom can make all the difference: gas-induced phase transformations in bisimidazole-linked diamondoid coordination networks

K Koupepidou, VI Nikolayenko… - Journal of the …, 2023 - ACS Publications
Coordination networks (CNs) that undergo gas-induced transformation from closed
(nonporous) to open (porous) structures are of potential utility in gas storage applications …

From macro-to nanoscale: finite size effects on metal–organic framework switchability

S Ehrling, H Miura, I Senkovska, S Kaskel - Trends in Chemistry, 2021 - cell.com
Switchable metal–organic frameworks (MOFs) standt out for potential applications in energy
storage, separation, sensing, and catalysis. The understanding of MOF switchability …