Asymmetric transition metal-catalyzed allylic alkylations

BM Trost, DL Van Vranken - Chemical Reviews, 1996 - ACS Publications
Efficient and reliable amplification of chirality has borne its greatest fruit with transition metal-
catalyzed reactions since enantiocontrol may often be imposed by replacing an achiral or …

Preparation of polymer-supported ligands and metal complexes for use in catalysis

NE Leadbeater, M Marco - Chemical Reviews, 2002 - ACS Publications
Recent interest in the development of environmentally benign synthesis has evoked a
renewed interest in developing polymer-bound metal catalysts and reagents for organic …

[PDF][PDF] Highly dispersed Pd catalyst locked in knitting aryl network polymers for Suzuki–Miyaura coupling reactions of aryl chlorides in aqueous media

B Li, Z Guan, W Wang, X Yang, J Hu, B Tan… - Advanced …, 2012 - researchgate.net
The porous materials with high surface area have attracted significant scientific attention due
to their diverse potential applications in separation,[1, 2] heterogeneous catalysis,[3] and …

Asymmetric catalysis at chiral metal surfaces

T Mallat, E Orglmeister, A Baiker - Chemical Reviews, 2007 - ACS Publications
The remarkable development in homogeneous enantioselective catalysis reflected by the
Nobel prizes in 2001 awarded to Sharpless, Noyori, and Knowles has further spurred the …

Recoverable catalysts and reagents using recyclable polystyrene-based supports

CA McNamara, MJ Dixon, M Bradley - Chemical reviews, 2002 - ACS Publications
The massive increase in use and the broadening range of applications for polymeric
supports in chemistry illustrate the immense significance of the technique to the chemist. The …

Metal catalyzed allylic alkylation: its development in the Trost laboratories

BM Trost - Tetrahedron, 2015 - Elsevier
I am highly honored to be the co-recipient of the Tetrahedron Prize for 2014 with Professor
Jiro Tsuji for our work on metal catalyzed allylic alkylation, notably that using palladium. In …

A modular approach for ligand design for asymmetric allylic alkylations via enantioselective palladium-catalyzed ionizations

BM Trost, DL Van Vranken, C Bingel - Journal of the American …, 1992 - ACS Publications
A new class of ligands for asymmetric transition metal catalysis based on 2-
(diphenylphosphino) benzoic acid was used in a mechanistically-defined palladium …

Multi-step organic synthesis using solid-supported reagents and scavengers: a new paradigm in chemical library generation

SV Ley, IR Baxendale, RN Bream… - Journal of the …, 2000 - pubs.rsc.org
The use of polymer-supported reagents and scavengers provides an attractive and practical
method for the clean and efficient preparation of novel chemical libraries with potential …

Enantioselective homogeneous catalysis involving transition-metal-allyl intermediates

G Consiglio, RM Waymouth - Chemical Reviews, 1989 - ACS Publications
The synthesis of enantiomerically pure compounds is an extremely important undertaking
and a formida-ble challenge to thesynthetic chemist. 1 The importance of enantiomerically …

[图书][B] Supported metal complexes: a new generation of catalysts

FR Hartley - 2012 - books.google.com
It is now IS years since the first patents in polymer supported metal complex catalysts were
taken out. In the early days ion-exchange resins were used to support ionic metal …