The spontaneous self-organization of matters has always been one of the most fascinating
wonders in the world. Self-assembly refers to “the autonomous organization of components …

Organic light-emitting diodes (OLEDs) are manufactured primarily by synthesizing five-
membered ring products using cyclometalation reactions. Highly photoluminescent quantum …

Luminescent metal complexes are key materials for several applications such as lighting,
analytical probes, and lasers. In many cases compounds based on precious (ie platinum …

Organometallic complexes (OMCs) consisting of organic and metal active moieties have
shown immense potential for application in solar cells. The diverse structure, rich porosity …

“Rollover” cyclometalation constitutes a special case among the well-known class of
cyclometalation reactions. An overview is given that covers the very first description of this …

The first direct mechanochemical transition-metal-mediated activation of strong phenyl C–H
bonds is reported. The mechanochemical procedure, resulting in cyclopalladated …

Reactions of 2-substituted pyridines HL with [MCl2Cp*] 2 (M= Ir, Rh) and [RuCl2 (p-cymene)]
2 have been carried out in the presence and absence of sodium acetate. 2-Phenylpyridine …

C H activation by acetate‐assisted cyclometallation of a phenyl group with half‐sandwich
complexes [{MCl2Cp*} 2](M= Ir, Rh) and [{RuCl2 (p‐cymene)} 2] can be directed by a wide …

The study of the reactivity of three 1-(2-dimethylaminoethyl)-1H-pyrazole derivatives of
general formula [1-(CH2) 2NMe2}-3, 5-R2-pzol]{where pzol represents pyrazole and RH …

Azobenzene is the most extensively used class of chromophore in a large variety of
applications. Recently, the use of azobenzene derivatives was developed in catalysis …