Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system

I Senkovska, V Bon, L Abylgazina, M Mendt… - Angewandte …, 2023 - Wiley Online Library
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …

A review on metal-organic frameworks photoelectrochemistry: A headlight for future applications

K Dashtian, S Shahbazi, M Tayebi… - Coordination Chemistry …, 2021 - Elsevier
Photoelectrochemistry is an advancing interdisciplinary field, dealing with the chemistry and
physics of photo-driven reactions at solid/liquid interfaces. This field requires collaboration …

Isotope-selective pore opening in a flexible metal-organic framework

L Bondorf, JL Fiorio, V Bon, L Zhang, M Maliuta… - Science …, 2022 - science.org
Flexible metal-organic frameworks that show reversible guest-induced phase transitions
between closed and open pore phases have enormous potential for highly selective, energy …

Multi-dimensional metal-organic frameworks based on mixed linkers: Interplay between structural flexibility and functionality

S Bhattacharyya, TK Maji - Coordination Chemistry Reviews, 2022 - Elsevier
Metal-organic frameworks (MOFs) are regarded widely because of their intriguing structural
dynamism, which sets them apart from other porous materials. Such structural flexibility or …

Unraveling structure and dynamics in porous frameworks via advanced in situ characterization techniques

V Bon, E Brunner, A Pöppl… - Advanced Functional …, 2020 - Wiley Online Library
Dynamic metal–organic frameworks (MOFs) represent a subgroup of frameworks featuring
unique performance, as they are capable of adapting their pore size and/or the orientation of …

From macro-to nanoscale: finite size effects on metal–organic framework switchability

S Ehrling, H Miura, I Senkovska, S Kaskel - Trends in Chemistry, 2021 - cell.com
Switchable metal–organic frameworks (MOFs) standt out for potential applications in energy
storage, separation, sensing, and catalysis. The understanding of MOF switchability …

Adaptive response of a metal–organic framework through reversible disorder–disorder transitions

S Ehrling, EM Reynolds, V Bon, I Senkovska… - Nature Chemistry, 2021 - nature.com
The ultrahigh porosity and varied functionalities of porous metal–organic frameworks make
them excellent candidates for applications that range widely from gas storage and …

Hybrid perovskites, metal–organic frameworks, and beyond: unconventional degrees of freedom in molecular frameworks

HLB Boström, AL Goodwin - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus The structural degrees of freedom of a solid material are the various distortions
most straightforwardly activated by external stimuli such as temperature, pressure, or …

Crystal size versus paddle wheel deformability: selective gated adsorption transitions of the switchable metal–organic frameworks DUT-8 (Co) and DUT-8 (Ni)

S Ehrling, I Senkovska, V Bon, JD Evans… - Journal of Materials …, 2019 - pubs.rsc.org
Switchable pillared layer metal–organic frameworks M2 (2, 6-ndc) 2 (dabco)(DUT-8 (M), M=
Ni, Co, 2, 6-ndc= 2, 6-naphthalenedicarboxylate, dabco= 1, 4-diazabicyclo-[2.2. 2] octane …

Impact of crystal size and morphology on switchability characteristics in pillared-layer metal-organic framework DUT-8 (Ni)

L Abylgazina, I Senkovska, R Engemann… - Frontiers in …, 2021 - frontiersin.org
Variation of the crystallite size in flexible porous coordination polymers can significantly
influence or even drastically change the flexibility characteristics. The impact of crystal …