Icosahedral boranes, carboranes, and metallacarboranes are extraordinarily robust
compounds with desirable properties such as thermal and redox stability, chemical …

Boron clusters and organic molecules display manifestly different electronic, physical,
chemical and geometrical characteristics. These differences highlight the complementarity of …

Although the majority of ligands in modern chemistry take advantage of carbon-based
substituent effects to tune the sterics and electronics of coordinating moieties, we describe …

Noted experts review the current status of boron-containing drugs and materials for
molecular medical diagnostics Boron-Based Compounds offers a summary of the present …

Intrinsically conducting polymers may undergo significant changes of molecular structure
and material properties when exposed to highly oxidizing conditions or very positive …

The synthesis of a highly twisted chrysene derivative incorporating two electron deficient o‐
carboranyl groups is reported. The molecule exhibits a complex, excitation‐dependent …

An approach to the design of nido‐carborane‐based luminescent compounds that can
exhibit thermally activated delayed fluorescence (TADF) is proposed. 7, 8‐Dicarba‐nido …

We have prepared the first examples of B9-connected trivalent aryl and alkyl
phosphinoborane species via Pd-catalyzed phosphination of 9-iodo-meta-carborane. Our …

This work demonstrates the first successful electrochemical cycling of a redox-active boron
cluster-based material in the solid state. Specifically, we designed and synthesized an ether …

Metalated three-dimensional icosahedral boron clusters often exhibit high chemical and
thermal stability relative to their simple borane counterparts thus making them a convenient …