[HTML][HTML] MLCT excited states of cuprous bis-phenanthroline coordination compounds

DV Scaltrito, DW Thompson, JA O'Callaghan… - Coordination Chemistry …, 2000 - Elsevier
Cuprous bis-phenanthroline compounds possess metal-to-ligand charge transfer, MLCT,
excited states. Phenanthroline ligands coordinated to Cu (I) that are disubstituted in the 2 …

Probing transient molecular structures in photochemical processes using laser-initiated time-resolved X-ray absorption spectroscopy

LX Chen - Annu. Rev. Phys. Chem., 2005 - annualreviews.org
▪ Abstract Molecular structures during chemical processes are crucial for predicting
molecular reactivity and reaction mechanisms. Using a laser pulse as an internal clock for …

Molecular rotors as fluorescent viscosity sensors: molecular design, polarity sensitivity, dipole moments changes, screening solvents, and deactivation channel of the …

F Zhou, J Shao, Y Yang, J Zhao, H Guo, X Li, S Ji… - 2011 - Wiley Online Library
A library of new fluorescent molecular rotors (FMRs) for viscosity sensing was synthesized.
The sensitivity of the fluorescence emission toward solvent viscosity and polarity was …

Time-resolved infra-red studies of photo-excited porphyrins in the presence of nucleic acids and in HeLa tumour cells: insights into binding site and electron transfer …

PM Keane, C Zehe, FE Poynton, SA Bright… - Physical Chemistry …, 2022 - pubs.rsc.org
Cationic porphyrins based on the 5, 10, 15, 20-meso-(tetrakis-4-N-methylpyridyl) core
(TMPyP4) have been studied extensively over many years due to their strong interactions …

Transient absorption and time-resolved vibrational studies of photophysical and photochemical processes in DNA-intercalating polypyridyl metal complexes or …

PM Keane, JM Kelly - Coordination Chemistry Reviews, 2018 - Elsevier
Recent advances in the use of transient absorption (TA) and time-resolved vibrational
spectroscopies (TRIR and TR 3) to study both excited states and reaction intermediates in …

EPR spectra, luminescence data, and radiationless decay processes of copper (II) porphyrins

KL Cunningham, KM McNett, RA Pierce… - Inorganic …, 1997 - ACS Publications
For a series of copper (II) porphyrins, we report EPR data from solid solutions as well as E 0
values for the first ring oxidation, emission spectra, and luminescence lifetimes in methylene …

Structural analysis of DNA-chlorophyll complexes by Fourier transform infrared difference spectroscopy

JF Neault, HA Tajmir-Riahi - Biophysical journal, 1999 - cell.com
Porphyrins and metalloporphyrins are strong DNA binders. Some of these compounds have
been used for radiation sensitization therapy of cancer and are targeted to interact with …

Tutorial review. Time-resolved resonance Raman spectroscopy

SEJ Bell - Analyst, 1996 - pubs.rsc.org
Vibrational Raman spectroscopy is now widely recognized as a useful technique for
chemical analysis. It has become increasingly popular for the characterization of stable …

[HTML][HTML] Diethylstilbestrol-DNA interaction studied by Fourier transform infrared and Raman spectroscopy

JF Neault, HA Tajmir-Riahi - Journal of Biological Chemistry, 1996 - Elsevier
The interaction of diethylstilbestrol (DES) with calf thymus DNA was investigated at
physiological pH with drug/DNA (phosphate) molar ratios (r) of 1: 40, 1: 20, 1: 10, 1: 4, 1: 2 …

DNA− chlorophyllin interaction

JF Neault, HA Tajmir-Riahi - The Journal of Physical Chemistry B, 1998 - ACS Publications
Porphyrins and their metal derivatives are strong DNA binders with association constants of
around 106 M-1. Some of these compounds have been used for radiation sensitization …