Nonclassical routes for amide bond formation

RM De Figueiredo, JS Suppo, JM Campagne - Chemical reviews, 2016 - ACS Publications
The present review offers an overview of nonclassical (eg, with no pre-or in situ activation of
a carboxylic acid partner) approaches for the construction of amide bonds. The review aims …

Transition-metal catalysed C–N bond activation

Q Wang, Y Su, L Li, H Huang - Chemical Society Reviews, 2016 - pubs.rsc.org
Transition-metal catalysed C–N bond activation has attracted much attention and become
one of the most promising bond disconnection and formation strategies that encompass a …

Synthesis of α, β-unsaturated carbonyl compounds by carbonylation reactions

S Zhang, H Neumann, M Beller - Chemical Society Reviews, 2020 - pubs.rsc.org
α, β-Unsaturated carbonyl compounds are key building blocks in organic chemistry. Their
catalytic synthesis has received significant attention during the past decades. Among the …

An update on oxidative C–H carbonylation with CO

Y Liu, YH Chen, H Yi, A Lei - ACS Catalysis, 2022 - ACS Publications
Carbonyl derivatives widely exist in pharmaceuticals, agricultural chemicals, materials, and
natural products. Developing novel, efficient, and green carbonylation methods represent …

Electrochemical palladium-catalyzed oxidative sonogashira carbonylation of arylhydrazines and alkynes to ynones

Y Wu, L Zeng, H Li, Y Cao, J Hu, M Xu… - Journal of the …, 2021 - ACS Publications
Oxidative carbonylation using carbon monoxide has evolved as an attractive tool to valuable
carbonyl-containing compounds, while mixing CO with a stoichiometric amount of a …

No making without breaking: nitrogen-centered carbonylation reactions

Z Yin, JX Xu, XF Wu - ACS Catalysis, 2020 - ACS Publications
Carbonylation, an efficient and straightforward approach for installing a carbonyl group into
their parent compounds, is an important area in modern organic synthesis. This Review …

Highly ligand-controlled regioselective Pd-catalyzed aminocarbonylation of styrenes with aminophenols

T Xu, F Sha, H Alper - Journal of the American Chemical Society, 2016 - ACS Publications
Achieving chemo-and regioselectivity simultaneously is challenging in organic synthesis.
Transition metal-catalyzed reactions are effective in addressing this problem by the diverse …

The lower the better: Efficient carbonylative reactions under atmospheric pressure of carbon monoxide

Q Tian, X Yin, R Sun, Y Li - Coordination Chemistry Reviews, 2023 - Elsevier
Carbon monoxide is an indispensable C1 building block that has been recognized as a
potent feedstock for synthesizing carbonyl-containing molecules. Carbonylative reactions …

Recent Advances in Copper‐Catalyzed C−N Bond Formation Involving N‐Centered Radicals

YN Zheng, H Zheng, T Li, WT Wei - ChemSusChem, 2021 - Wiley Online Library
C− N bonds are pervasive throughout organic‐based materials, natural products,
pharmaceutical compounds, and agricultural chemicals. Considering the widespread …

Selective Palladium‐Catalyzed Aminocarbonylation of Olefins to Branched Amides

J Liu, H Li, A Spannenberg, R Franke… - Angewandte Chemie …, 2016 - Wiley Online Library
A general and efficient protocol for iso‐selective aminocarbonylation of olefins with aliphatic
amines has been developed for the first time. Key to the success for this process is the use of …