Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

Interelement compounds, that is, compounds containing an interelement bond, 1 are
attractive main group element precursors as these provide the opportunity to transfer both …

In 1963 Shriver reported a metal-boron dative bond in a complex formulated as [(η5-C5H5)
2WH2 (BF3)]. 33 However, these findings were refuted around 30 years later when differing …

The well-defined copper (I) boryl complex [(IPr) Cu (Bpin)][where IPr= 1, 3-bis (2, 6-
diisopropylphenyl) imidazol-2-ylidene, and pin= pinacolate: 2, 3-dimethyl-2, 3 …

Despite the widespread use of organoborane reagents in organic synthesis and catalysis, a
major challenge still remains: very few boron-centered nucleophiles exist for the direct …

Multi (boronate) esters have been attracting increasing attention as versatile building blocks
for the succinct and precise synthesis of complex molecules. However, there are a limited …

Additions of homoelement-element and heteroelementelement linkages to unsaturated
substrates catalyzed by the platinum group metals constitute synthetically highly versatile …