Synthetic approaches for multiblock copolymers

VP Beyer, J Kim, CR Becer - Polymer Chemistry, 2020 - pubs.rsc.org
Multiblock copolymers (MBCs) are an emerging class of synthetic polymers that exhibit
different macromolecular architectures and behaviours to those of homopolymers or …

Fluorescence-readout as a powerful macromolecular characterisation tool

X Wu, C Barner-Kowollik - Chemical Science, 2023 - pubs.rsc.org
The last few decades have witnessed significant progress in synthetic macromolecular
chemistry, which can provide access to diverse macromolecules with varying structural …

Synthesis of Cleavable Polymers via Oxidation of Thioether Moieties and Thiol Click Reactions: A Click‐Declick Strategy

L Wang, L Liu, H Zhao - Angewandte Chemie International …, 2023 - Wiley Online Library
In the past decades click chemistries including thiol chemistries have found wide
applications in the synthesis of well‐defined polymers. In this research, a click‐declick …

Stereocontrolled, multi-functional sequence-defined oligomers through automated synthesis

C Mertens, M Soete, ML Ślęczkowski… - Polymer …, 2020 - pubs.rsc.org
In contrast to biomacromolecules, synthetic polymers generally lack a defined monomer
sequence, therefore one of the challenges of polymer chemists these days is gaining more …

Self-Healing and Adhesive Supersoft Materials Derived from Dynamically Cross-Linked Bottlebrush Polymers for Flexible Sensors

E Du, M Li, B Xu, Y Zhang, Z Li, X Yu, X Fan - Macromolecules, 2024 - ACS Publications
Multifunctional bottlebrush polymer supersoft materials are highly desirable for the
development of next-generation flexible electronic devices. Herein, we report a facile …

Assembling Complex Macromolecules and Self-Organizations of Biological Relevance with Cu (I)-Catalyzed Azide-Alkyne, Thio-Bromo, and TERMINI Double “Click” …

A Moreno, G Lligadas, J Adamson, DS Maurya… - Polymers, 2023 - mdpi.com
In 2022, the Nobel Prize in Chemistry was awarded to Bertozzi, Meldal, and Sharpless “for
the development of click chemistry and biorthogonal chemistry”. Since 2001, when the …

Hybrid Multiblock Copolymers of 2-Oxazoline and Acrylates via Cu-Catalyzed Azide–Alkyne Cycloaddition Step-Growth Mechanism

G Hayes, B Drain, J Lefley, CR Becer - Macromolecules, 2022 - ACS Publications
Multiblock copolymers exhibit interesting self-assembly behaviors owing to their repetitive
block structure. Incompatible chemical structures of each block enable unprecedented self …

[HTML][HTML] Resolving the incompatibility between SET-LRP and non-disproportionating solvents

N Bensabeh, A Moreno, DS Maurya, J Adamson… - Giant, 2023 - Elsevier
Abstract Cu (0)-catalyzed single-electron transfer-living radical polymerization (SET-LRP)
has shown great potential for applications in which well-defined chain end-functionalized …

One-pot cascade polycondensation and Passerini three-component reactions for the synthesis of functional polyesters

B Alkan, O Daglar, S Luleburgaz, B Gungor… - Polymer …, 2022 - pubs.rsc.org
Herein, we present a one-pot cascade reaction for the synthesis and simultaneous
modification of polyesters. Pyromellitic dianhydride (PMDA) was reacted with a variety of …

Synthesis of fully degradable cationic polymers with various topological structures via postpolymerization modification by using thio-bromo “click” reaction

Y Dai, Z Hu, X Wang, X Liu, Y Li, Y Shi, Y Chen - Polymer Chemistry, 2021 - pubs.rsc.org
Synthesis of cationic polymers possessing significant therapeutic potential is of tremendous
research interest. Here, we report a facile synthesis of poly (ε-caprolactone)(PCL) based …