Despite the difficulties associated with controlling the polymerization of ring-strained
nitrogen containing monomers, the resulting polymers have many important applications …

This review describes recent progress in the development of homogeneous, metal-
mediated, catalytic pathways to synthetically valuable aziridines and sulfonamides. Areas of …

Strong reducing agents (<− 2.0 V vs saturated calomel electrode (SCE)) enable a wide array
of useful organic chemistry, but suffer from a variety of limitations. Stoichiometric metallic …

Due to their ready availability in chiral form, and propensity to undergo regio-and
stereoselective ring opening, aziridines have found widespread use in asymmetric …

Primary amines are essential constituents of biologically active molecules and versatile
intermediates in the synthesis of drugs and agrochemicals. However, their preparation from …

Catalytic aziridination of alkenes with nitrene sources via “C2+ N1” addition represents a
general approach for the direct synthesis of aziridines, the smallest three-membered N …

Instantaneous Deprotection of Tosylamides and Esters with SmI2/Amine/Water | Organic
Letters ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters ACS …

An asymmetric para‐C (sp2)− H bond functionalization of alkyl benzene derivatives was
successfully developed via cooperative catalysis of gold and chiral phosphoric acid (CPA) …

The mechanism of the copper-catalyzed aziridination of alkenes using [N-(p-toluenesulfonyl)
imino] phenyliodinane (PhINTs) as the nitrene source has been elucidated by a combination …

Structurally related to iodosylbenzene PhI= O, iodonium imidesPhI= NR, off-white to pale
yellow solids of low solubility, belongto the class of hypervalent iodine (III) reagents and …