Recent developments in the synthesis and utilization of chiral sulfoxides

I Fernández, N Khiar - Chemical reviews, 2003 - ACS Publications
The interest in chiral tricoordinated sulfur compounds in general, and sulfoxides in
particular, has shifted from purely academic, directed toward the study of their …

Baeyer− Villiger monooxygenases: more than just green chemistry

H Leisch, K Morley, PCK Lau - Chemical reviews, 2011 - ACS Publications
What is life without oxygen is a rhetorical question. On the other hand, unraveling the
intricacies and understanding the various mechanisms underpinning the biological …

[图书][B] Enzyme catalysis in organic synthesis, 3 volume set

K Drauz, H Gröger, O May - 2012 - books.google.com
This comprehensive three-volume set is the standard reference in the field of organic
synthesis, catalysis and biocatalysis. Edited by a highly experienced and highly …

Mammalian flavin-containing monooxygenases: structure/function, genetic polymorphisms and role in drug metabolism

SK Krueger, DE Williams - Pharmacology & therapeutics, 2005 - Elsevier
Flavin-containing monooxygenase (FMO) oxygenates drugs and xenobiotics containing a
“soft-nucleophile”, usually nitrogen or sulfur. FMO, like cytochrome P450 (CYP), is a …

Baeyer–Villiger monooxygenases: tunable oxidative biocatalysts

MJLJ Fürst, A Gran-Scheuch, FS Aalbers… - ACS …, 2019 - ACS Publications
Pollution, accidents, and misinformation have earned the pharmaceutical and chemical
industry a poor public reputation, despite their undisputable importance to society …

Applications of catalytic asymmetric sulfide oxidations to the syntheses of biologically active sulfoxides

J Legros, JR Dehli, C Bolm - Advanced Synthesis & Catalysis, 2005 - Wiley Online Library
Optically active sulfoxides are important compounds for medicinal and pharmaceutical
chemistry. Driven by the increasing demand for efficient, selective and environmentally …

Molecular mechanisms of biocatalytic desulfurization of fossil fuels

KA Gray, OS Pogrebinsky, GT Mrachko, L Xi… - Nature …, 1996 - nature.com
The development of biocatalytic desulfurization of petroleum fractions may allow its use in
place of conventional hydrodesulfurization (HDS). Dibenzothiophene (DBT) is …

Mechanistic studies of cyclohexanone monooxygenase: chemical properties of intermediates involved in catalysis

D Sheng, DP Ballou, V Massey - Biochemistry, 2001 - ACS Publications
Cyclohexanone monooxygenase (CHMO), a bacterial flavoenzyme, carries out an oxygen
insertion reaction on cyclohexanone to form a seven-membered cyclic product, ε …

Recent developments in the application of Baeyer–Villiger monooxygenases as biocatalysts

G de Gonzalo, MD Mihovilovic, MW Fraaije - ChemBioChem, 2010 - Wiley Online Library
Abstract Baeyer–Villiger monooxygenases (BVMOs) represent a specific class of
monooxygenases that are capable of catalyzing a variety of oxidation reactions, including …

From molecular diversity to catalysis: lessons from the immune system

PG Schultz, RA Lerner - Science, 1995 - science.org
By combining the enormous molecular diversity of the immune system with basic
mechanistic principles of chemistry, one can produce catalytic antibodies that allow control …