Current medicinal chemistry relies heavily on the quality of building blocks, ie reagents used
to introduce chemical diversity into the target molecules. The last decade witnessed an …

The use of sulfinic acids and their salts continues to be extensively developed in organic
chemistry. This is attributable to their dual capacity for acting as nucleophilic or electrophilic …

The coupling of aryldiazonium tetrafluoroborates, DABCO⋅(SO2) 2, and hydrazines under
metal‐free conditions leads to the formation of aryl N‐aminosulfonamides. The reaction …

Both arylsulfonyl and alkylsulfonyl azides can be effectively activated by the cobalt (II)
complexes of D 2-symmetric chiral amidoporphyrins for enantioselective radical 1, 5-C–H …

A photoredox‐catalyzed three‐component synthesis of N‐aminosulfonamides starting from
diaryliodonium salts, hydrazines and sulfur dioxide is reported. This reaction proceeds …

The first described reaction between N-tosylhydrazone and SO2 is reported to provide alkyl
sulfonamides in the presence of various amines. In this procedurally simple method …

A new flow procedure for the preparation of arylsulfonyl chlorides from aniline starting
materials is described. The reaction conditions are mild, requiring no added acid and are …

Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic
Acids | Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my …

A copper (II)-catalyzed three-component reaction of 2, 3-allenoic acids, sulfur dioxide, and
aryldiazonium tetrafluoroborates under mild conditions is developed, leading to 4 …

Sulfonyl fluorides are known to inhibit esterases. Early work from our laboratory has
identified hexadecyl sulfonylfluoride (AM374) as a potent in vitro and in vivo inhibitor of fatty …