The reduction of Cr (VI) to Cr (III) mediated by environmentally relevant carboxylic acids: state-of-the-art and perspectives
B Jiang, Y Gong, J Gao, T Sun, Y Liu, N Oturan… - Journal of Hazardous …, 2019 - Elsevier
The detoxification process mediated by carboxylic acids (CAs) has received considerable
spotlights since CAs are clean reagent and ubiquitous in the natural environments and …
spotlights since CAs are clean reagent and ubiquitous in the natural environments and …
Methods utilizing first-row transition metals in natural product total synthesis
JE Zweig, DE Kim, TR Newhouse - Chemical Reviews, 2017 - ACS Publications
First-row transition-metal-mediated reactions constitute an important and growing area of
research due to the low cost, low toxicity, and exceptional synthetic versatility of these …
research due to the low cost, low toxicity, and exceptional synthetic versatility of these …
Insight into the Key Role of Cr Intermediates in the Efficient and Simultaneous Degradation of Organic Contaminants and Cr(VI) Reduction via gC3N4-Assisted …
S Zhang, H Lan, Y Cui, X An, H Liu… - Environmental Science & …, 2022 - ACS Publications
Photocatalysis provides an impetus for the synergetic removal of Cr (VI) and organic
contaminants, but the generation of Cr intermediates and their potential oxidizability may be …
contaminants, but the generation of Cr intermediates and their potential oxidizability may be …
Surface-catalyzed chromium (VI) reduction: reactivity comparisons of different organic reductants and different oxide surfaces
CrVI reduction by low molecular weight organic compounds with various functional groups
was examined in the presence and absence of oxide surfaces. Surface-catalyzed CrVI …
was examined in the presence and absence of oxide surfaces. Surface-catalyzed CrVI …
Insights into the oxidation of organic cocontaminants during Cr (VI) reduction by sulfite: the overlooked significance of Cr (V)
Literature works reported that organic cocontaminants could be degraded during Cr (VI), a
contaminant, reduction by sulfite (Cr (VI)/sulfite process). However, the role of Cr (V) and Cr …
contaminant, reduction by sulfite (Cr (VI)/sulfite process). However, the role of Cr (V) and Cr …
Mechanistic studies of relevance to the biological activities of chromium
Cellular uptake of Cr (VI), followed by its reduction to Cr (III) with the formation of reactive Cr
(V/IV) intermediates, is a generally accepted cause of Cr (VI)-induced genotoxicity and …
(V/IV) intermediates, is a generally accepted cause of Cr (VI)-induced genotoxicity and …
Studies on the genotoxicity of chromium: from the test tube to the cell
A critical review of the relevance of in vitro chemical studies to Cr-induced cancers is given.
In particular, the nature of the most likely reductants, the species that stabilise intermediates …
In particular, the nature of the most likely reductants, the species that stabilise intermediates …
Reduction of chromium (VI) by ascorbate leads to chromium-DNA binding and DNA strand breaks in vitro
DM Stearns, LJ Kennedy, KD Courtney… - Biochemistry, 1995 - ACS Publications
Revised Manuscript Received November 7, 1994s abstract: Chromium (VI) is a known
human carcinogen which requires intracellular reduction for activation. Ascorbate (vitamin …
human carcinogen which requires intracellular reduction for activation. Ascorbate (vitamin …
Two-phase total synthesis of taxanes: tactics and strategies
Y Kanda, Y Ishihara, NC Wilde… - The Journal of Organic …, 2020 - ACS Publications
This Perspective goes into the fine details of our laboratory's quest to answer a longstanding
fundamental question: Could any new approach to terpene synthesis, perhaps one …
fundamental question: Could any new approach to terpene synthesis, perhaps one …
Reaction of chromium (VI) with ascorbate produces chromium (V), chromium (IV), and carbon-based radicals
DM Stearns, KE Wetterhahn - Chemical research in toxicology, 1994 - ACS Publications
Reaction of potassium dichromate with sodium ascorbate was studied by EPR spectroscopy
at room temperature, in 0.10 M. ZV-[2-hydroxyethyl] piperazine-. ZV'-[2-ethanesulfonic …
at room temperature, in 0.10 M. ZV-[2-hydroxyethyl] piperazine-. ZV'-[2-ethanesulfonic …