232Th-Spallation-Produced 225Ac with Reduced 227Ac Content

AKH Robertson, BL McNeil, H Yang… - Inorganic …, 2020 - ACS Publications
Recent clinical results have demonstrated remarkable treatment responses of late-stage
cancer patients when treated with alpha-emitting radionuclides such as actinium-225 …

Silver ion-induced formation of unprecedented thorium nonamer clusters via lacuna-construction strategy

XH Kong, QY Wu, L Mei, LW Zeng, ZW Huang… - CCS …, 2023 - chinesechemsoc.org
Herein, we report the synthesis and structures of two novel mixed-metal clusters denoted as
Th9Ag6 and Th9Ag12. Both clusters feature unprecedented Th9 cores. The cores are …

Chronicles of plutonium peroxides: spectroscopic characterization of a new peroxo compound of Pu (iv)

J Margate, S Bayle, T Dumas, E Dalodière… - Chemical …, 2024 - pubs.rsc.org
Although hydrogen peroxide (H2O2) has been highly used in nuclear chemistry for more
than 75 years, the preparation and literature description of tetravalent actinide peroxides …

Monomeric and trimeric thorium chlorides isolated from acidic aqueous solution

JN Wacker, M Vasiliu, I Colliard, RL Ayscue III… - Inorganic …, 2019 - ACS Publications
Two thorium (IV) compounds,[Th (H2O) 4Cl4]· 2 (HPy· Cl)(1) and (HPy) 3 [Th3 (H2O) 2Cl10
(OH) 5]· 4 (HPy· Cl)(2)(HPy= pyridinium), were isolated from acidic aqueous solution. The …

Tetranuclear oxido-bridged thorium (IV) clusters obtained using tridentate Schiff bases

ST Tsantis, A Lagou-Rekka, KF Konidaris… - Dalton …, 2019 - pubs.rsc.org
Thorium (IV) complexes are currently attracting intense attention from inorganic chemists
due to the development of liquid-fluoride thorium reactors and the fact that thorium (IV) is …

Deciphering the crystal structure of a scarce 1D polymeric thorium peroxo sulfate

L Bonato, M Virot, T Dumas, A Mesbah… - … A European Journal, 2019 - Wiley Online Library
The preparation and structural characterization of an original Th peroxo sulfate dihydrate,
crystallizing at room temperature in the form of stable 1D polymeric microfibres is described …

Pentanuclear thorium (IV) coordination cluster from the use of di (2-pyridyl) ketone

ST Tsantis, P Danelli, DI Tzimopoulos… - Inorganic …, 2021 - ACS Publications
The Th (NO3) 4· 5H2O/di (2-pyridyl) ketone [(py) 2CO] reaction system gives a pentanuclear
cluster containing the doubly deprotonated form of the gem-diol derivative of the ligand. The …

Breaking a Paradigm: Observation of Magnetic Order in the Purple U(IV) Phosphite: U(HPO3)2

JB Felder, MD Smith, HC Zur Loye - Inorganic Chemistry, 2018 - ACS Publications
The hydrothermal crystal growth of a new uranium phosphite, U (HPO3) 2, is reported. This
material was found to exhibit optical and magnetic properties not commonly observed in U …

Hydrothermal Synthesis: A Gateway To Metastable Crystals With Unusual Properties

JB Felder - 2018 - search.proquest.com
Research into crystalline matter has long been of interest to humanity, both in order to
advance our society by creating new technologically useful materials and in order to better …

Preparation and structural characterization of an original peroxide complex of Pu (IV)

J Margate, S Bayle, T Dumas, C Tamain… - JDA 2024-53rd …, 2024 - hal.science
Forecasting the behavior of radionuclides within the geosphere or deep underground
storage facilities necessitates a comprehensive grasp of the species that may arise when …